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Tin(II) chloride (CAS 7772-99-8)

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Alternate Names:
Stannous chloride; Dichlorotin; Tin protochloride
Application:
Tin(II) chloride is a tin preparation used as a laboratory reductant
CAS Number:
7772-99-8
Purity:
≥98%
Molecular Weight:
189.62
Molecular Formula:
SnCl2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Tin(II) chloride, with the chemical formula SnCl2, serves as a crucial reagent in scientific research due to its versatile properties and diverse applications across various disciplines. One of its primary mechanisms of action lies in its role as a reducing agent and a catalyst in organic synthesis. Tin(II) chloride′s ability to donate tin(II) ions makes it invaluable in promoting a variety of chemical transformations, including reductions of functional groups such as nitro groups to amines, carbonyl compounds to alcohols, and halides to organotin compounds. Moreover, tin(II) chloride finds extensive use as a precursor for the synthesis of tin-based materials and nanoparticles, where its controlled reduction properties allow for the preparation of nanocrystalline tin and tin oxide materials with tailored properties for applications in catalysis, sensing, and energy storage. Additionally, research efforts have explored its potential in the field of metallurgy, where it serves as a key component in the purification of tin and the extraction of rare metals from ores. Furthermore, tin(II) chloride has been investigated for its role in electroplating processes, where it acts as a source of tin ions for the deposition of tin coatings on metal surfaces. Overall, tin(II) chloride continues to be a pivotal component in scientific investigations, owing to its diverse functionalities and broad utility in research applications spanning organic synthesis, materials science, metallurgy, and electrochemistry.


Tin(II) chloride (CAS 7772-99-8) References

  1. New evidence for the mechanism of the tin(II) chloride catalyzed reactions of vicinal diols with diazodiphenylmethane in 1,2-dimethoxyethane.  |  Pétursson, S. 2001. Carbohydr Res. 331: 239-45. PMID: 11383893
  2. Efficient and convenient synthesis of pyrrolo[1,2-a]quinazoline derivatives with the aid of tin(II) chloride.  |  Wang, M., et al. 2010. J Comb Chem. 12: 582-6. PMID: 20545357
  3. Tin(II) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement.  |  Bandyopadhyay, A., et al. 2010. Org Biomol Chem. 8: 4855-60. PMID: 20734011
  4. Benzotriazolate cage complexes of tin(II) and lithium: halide-influenced serendipitous assembly.  |  Sulway, SA., et al. 2011. Dalton Trans. 40: 7559-63. PMID: 21695328
  5. The influence of cobalt(II) and tin(II) chloride on regioselectivity and kinetics of phenylselenocyclization of 6-methyl-hept-5-en-2-ol.  |  Divac, VM., et al. 2019. J Mol Model. 25: 158. PMID: 31089816
  6. Mechanosynthesis of Odd-Numbered Tetraaryl[n]cumulenes.  |  Ardila-Fierro, KJ., et al. 2019. Angew Chem Int Ed Engl. 58: 12945-12949. PMID: 31265746
  7. First synthesis of acylated nitrocyclopropanes.  |  Iwai, K., et al. 2023. Beilstein J Org Chem. 19: 892-900. PMID: 37377773
  8. Tin(II) Chloride-Catalyzed Direct Esterification and Amidation of tert-Butyl Esters Using α,α-Dichlorodiphenylmethane Under Mild Conditions.  |  Tran, VH., et al. 2023. J Org Chem. 88: 13291-13302. PMID: 37641453
  9. Tin (II) Chloride Salt Melts as Non-Innocent Solvents for the Synthesis of Low-Temperature Nanoporous Oxo-Carbons for Nitrate Electrochemical Hydrogenation.  |  Zheng, X., et al. 2024. Adv Mater. 36: e2311575. PMID: 38152896

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Tin(II) chloride, 100 g

sc-203413
100 g
$56.00

Tin(II) chloride, 500 g

sc-203413A
500 g
$150.00

Tin(II) chloride, 2.5 kg

sc-203413B
2.5 kg
$379.00