Date published: 2025-11-4

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Sodium peroxide (CAS 1313-60-6)

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Alternate Names:
Sodium superoxide
Application:
Sodium peroxide is a powerful oxidizing compound used in laboratory applications
CAS Number:
1313-60-6
Molecular Weight:
77.98
Molecular Formula:
O22Na
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Available in US only.
* Refer to Certificate of Analysis for lot specific data.

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Sodium periodate (NaIO4) plays a pivotal role in scientific research, particularly in the realms of organic chemistry and materials science. One of its primary mechanisms of action lies in its potent oxidizing properties, which have been extensively harnessed in various research applications. Specifically, sodium periodate is renowned for its ability to selectively cleave vicinal diols, yielding aldehydes or ketones. This mechanism finds wide utility in organic synthesis, facilitating the preparation of complex chemical intermediates and structurally diverse molecules. Additionally, sodium periodate has garnered attention in carbohydrate chemistry, where it serves as a versatile tool for the modification and functionalization of polysaccharides and glycoproteins. Its ability to oxidize specific hydroxyl groups in carbohydrates enables the controlled derivatization of these biomolecules, leading to the synthesis of tailored carbohydrate-based materials with desired properties. Furthermore, sodium periodate has been explored in the field of materials science, where it contributes to the synthesis of nanostructured materials and functional surfaces. Its compatibility with various substrates and its relatively mild reaction conditions make it an indispensable reagent for diverse research endeavors, spanning organic synthesis, carbohydrate chemistry, and materials science.


Sodium peroxide (CAS 1313-60-6) References

  1. Insights on Electrochemical Behaviors of Sodium Peroxide as a Sacrificial Cathode Additive for Boosting Energy Density of Na-Ion Battery.  |  Guo, YJ., et al. 2021. ACS Appl Mater Interfaces. 13: 2772-2778. PMID: 33400478
  2. Theoretical predictions for low-temperature phases, softening of phonons and elastic stiffnesses, and electronic properties of sodium peroxide under high pressure.  |  Jimlim, P., et al. 2019. RSC Adv. 9: 30964-30975. PMID: 35529358
  3. Alkali-induced decomposition of hydrogen peroxide  |  Galbács, Z. M., & Csányi, L. J. 1983. Journal of the Chemical Society, Dalton Transactions. (11): 2353-2357.
  4. Determination of platinum group elements and gold in geological samples with ICP-MS using a sodium peroxide fusion and tellurium co-precipitation  |  **, X., & Zhu, H. 2000. Journal of analytical atomic spectrometry. 15(6): 747-751.
  5. Determination of rare earth elements, Y, Th, Zr, Hf, Nb and Ta in geological reference materials G‐2, G‐3, SCo‐1 and WGB‐1 by sodium peroxide sintering and inductively coupled plasma‐mass spectrometry  |  Meisel, T., Schöner, N., Paliulionyte, V., & Kahr, E. 2002. Geostandards newsletter. 26(1): 53-61.
  6. Highly Diastereoselective Epoxidation of α,β-Unsaturated Carbonyl Compounds Using Sodium Peroxide  |  Reddy, V. K., Haritha, B., & Yamashita, M. 2005. Letters in Organic Chemistry. 2(2): 128-131.
  7. How to Control the Discharge Product in Sodium–Oxygen Batteries: Proposing New Pathways for Sodium Peroxide Formation  |  Schröder, D., Bender, C. L., Pinedo, R., Bartuli, W., Schwab, M. G., Tomović, Ž., & Janek, J. 2017. Energy Technology. 5(8): 1242-1249.
  8. Method development and optimisation of sodium peroxide sintering for geological samples  |  Bokhari, S. N. H., & Meisel, T. C. 2017. Geostandards and Geoanalytical Research. 41(2): 181-195.
  9. Rapid boron isotope and concentration measurements of silicate geological reference materials dissolved through sodium peroxide sintering  |  Cai, Y., Rasbury, E. T., Wooton, K. M., Jiang, X., & Wang, D. 2021. Journal of Analytical Atomic Spectrometry. 36(10): 2153-2163.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Sodium peroxide, 50 g

sc-203400
50 g
$96.00
US: Only available in the US

Sodium peroxide, 100 g

sc-203400A
100 g
$159.00
US: Only available in the US

Sodium peroxide, 500 g

sc-203400B
500 g
$575.00
US: Only available in the US