Date published: 2026-5-7

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Vinylene carbonate (CAS 872-36-6)

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Alternate Names:
1,3-dioxol-2-one; VC
CAS Number:
872-36-6
Purity:
≥99%
Molecular Weight:
86.05
Molecular Formula:
C3H2O3
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Vinylene Carbonate, the smallest unsaturated cyclic carbonic acid ester, finds application as an additive in electrolyte solutions for Lithium-ion and Sodium-ion batteries. Moreover, vinylene carbonate exhibits biocompatible properties, rendering it suitable for various biomedical applications. While sharing a polymer structure akin to polyvinylene (PV), vinylene carbonate demonstrates superior stability at elevated temperatures compared to PV. This enhanced thermal stability expands its potential uses in demanding environments.


Vinylene carbonate (CAS 872-36-6) References

  1. Understanding Fluoroethylene Carbonate and Vinylene Carbonate Based Electrolytes for Si Anodes in Lithium Ion Batteries with NMR Spectroscopy.  |  Jin, Y., et al. 2018. J Am Chem Soc. 140: 9854-9867. PMID: 29979869
  2. Synthesis of Arylacetaldehydes by Iridium-Catalyzed Arylation of Vinylene Carbonate with Arylboronic Acids.  |  Wang, Z., et al. 2019. Angew Chem Int Ed Engl. 58: 11054-11057. PMID: 31192491
  3. Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy.  |  Xu, Y., et al. 2020. Nano Lett. 20: 418-425. PMID: 31816244
  4. Ruthenium(II)-Catalyzed C-C/C-N Coupling of 2-Arylquinazolinones with Vinylene Carbonate: Access to Fused Quinazolinones.  |  Wang, ZH., et al. 2021. Org Lett. 23: 995-999. PMID: 33502206
  5. Vinylene carbonate: beyond the ethyne surrogate in rhodium-catalyzed annulation with amidines toward 4-methylquinazolines.  |  Wang, C., et al. 2021. Chem Commun (Camb). 57: 3929-3932. PMID: 33871531
  6. Synthesis of (2H)-Indazoles and Dihydrocinnolinones through Annulation of Azobenzenes with Vinylene Carbonate under Rh(III) Catalysis.  |  Park, MS., et al. 2021. Org Lett. 23: 5518-5522. PMID: 34228466
  7. Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification.  |  Kato, M., et al. 2021. Chem Commun (Camb). 57: 8280-8283. PMID: 34319322
  8. Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines.  |  Hu, Y., et al. 2021. Org Lett. 23: 8527-8532. PMID: 34670369
  9. Synthesis of oxazolidinones through ring-opening and annulation of vinylene carbonate with 2-pyrrolyl/indolylanilines under Rh(III) catalysis.  |  Hu, FP., et al. 2021. Chem Commun (Camb). 57: 11980-11983. PMID: 34709263
  10. Rhodium-Catalyzed C-H Annulation of Free Anilines with Vinylene Carbonate as a Bifunctional Synthon.  |  Nan, J., et al. 2021. Org Lett. 23: 8910-8915. PMID: 34757750
  11. High-speed C-H chlorination of ethylene carbonate using a new photoflow setup.  |  Kasakado, T., et al. 2022. Beilstein J Org Chem. 18: 152-158. PMID: 35140816
  12. Ruthenium-catalyzed oxidative coupling of vinylene carbonate with isoxazoles: access to fused anthranils.  |  Kumar, P. and Kapur, M. 2022. Chem Commun (Camb). 58: 4476-4479. PMID: 35297924
  13. Rh(III)-Catalyzed Synthesis of Indazolo[2,3-a]quinolines: Vinylene Carbonate as C1 and C2 Building Blocks.  |  Hu, W., et al. 2022. Org Lett. 24: 2613-2618. PMID: 35377649
  14. Effect of vinylene carbonate on SEI formation on LiMn2O4 in carbonate-based electrolytes.  |  Phan, QTN., et al. 2022. Phys Chem Chem Phys. 24: 25611-25619. PMID: 36254777

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Vinylene carbonate, 5 g

sc-251428
5 g
$230.00

Vinylene carbonate, 25 g

sc-251428A
25 g
$428.00