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Tris(dibenzylideneacetone)dipalladium(0) (CAS 51364-51-3)

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Alternate Names:
Bis[tris(dibenzylideneacetone)palladium(0)]
Application:
Tris(dibenzylideneacetone)dipalladium(0) is a cycloaddition catalyst
CAS Number:
51364-51-3
Molecular Weight:
915.72
Molecular Formula:
C51H42O3Pd2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Tris(dibenzylideneacetone)dipalladium(0) is a catalyst. Tris(dibenzylideneacetone)dipalladium(0)′s mechanism of action involves coordinating with the substrate to facilitate the formation of carbon-carbon and carbon-heteroatom bonds. Tris(Dibenzylideneacetone)Dipalladium(0) acts as a source of palladium(0) in cross-coupling reactions, enabling the coupling of aryl halides with organoboron reagents. Through its coordination with the reactants, it promotes the oxidative addition of aryl halides to palladium, leading to the formation of reactive intermediates that undergo further coupling reactions.


Tris(dibenzylideneacetone)dipalladium(0) (CAS 51364-51-3) References

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  4. Synthesis and reactivity of silylated tetrathiafulvalenes.  |  Hameau, A., et al. 2008. Dalton Trans. 4866-76. PMID: 18766219
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  6. Asymmetric synthesis of (-)-aurantioclavine via palladium-catalyzed intramolecular allylic amination.  |  Suetsugu, S., et al. 2014. Org Lett. 16: 996-9. PMID: 24460216
  7. One-pot organometallic synthesis of alumina-embedded Pd nanoparticles.  |  Costa, NJS., et al. 2017. Dalton Trans. 46: 14318-14324. PMID: 29019367
  8. 3D designed and printed chemical generators for on demand reagent synthesis.  |  Zalesskiy, SS., et al. 2019. Nat Commun. 10: 5496. PMID: 31792220
  9. Differences in the Performance of Allyl Based Palladium Precatalysts for Suzuki-Miyaura Reactions.  |  Espinosa, MR., et al. 2020. Adv Synth Catal. 362: 5062-5078. PMID: 33384575
  10. Tris(dibenzylideneacetone)dipalladium(0) (Tris DBA) Abrogates Tumor Progression in Hepatocellular Carcinoma and Multiple Myeloma Preclinical Models by Regulating the STAT3 Signaling Pathway.  |  Arora, L., et al. 2021. Cancers (Basel). 13: PMID: 34771643
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  13. Efficient pure blue hyperfluorescence devices utilizing quadrupolar donor-acceptor-donor type of thermally activated delayed fluorescence sensitizers.  |  Lee, H., et al. 2023. Nat Commun. 14: 419. PMID: 36697409

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Tris(dibenzylideneacetone)dipalladium(0), 500 mg

sc-253790
500 mg
$55.00

Tris(dibenzylideneacetone)dipalladium(0), 1 g

sc-253790A
1 g
$105.00

Tris(dibenzylideneacetone)dipalladium(0), 10 g

sc-253790B
10 g
$617.00

Tris(dibenzylideneacetone)dipalladium(0), 50 g

sc-253790C
50 g
$3063.00