Tris(2,6-dimethoxyphenyl)phosphine (CAS 85417-41-0)
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Tris(2,6-dimethoxyphenyl)phosphine is an organophosphorus compound that serves as a ligand in coordination chemistry, facilitating the study of transition metal complexes. Its bulky aryl groups are instrumental for researchers exploring steric effects on catalytic activity, which is essential for understanding and designing new catalysts. In materials science, this chemical′s ability to donate electrons to metal centers is utilized in the investigation of conductive and magnetic properties of metal-organic frameworks. Moreover, it′s often used in the exploration of novel photophysical properties of phosphine-metal complexes, which has implications for the development of light-emitting materials. The compound′s structural features also make it a subject of interest in the study of molecular recognition processes, which are fundamental to the development of sensors and separation technologies.
Tris(2,6-dimethoxyphenyl)phosphine (CAS 85417-41-0) References
- Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir(CO)(PR(3)) Complexes. | Wang, D. and Angelici, RJ. 1996. Inorg Chem. 35: 1321-1331. PMID: 11666327
- Reactions of [(eta(6)-arene)RuCl(2)](2) with Aromatic Phosphines Containing Methoxy Groups in 2,6-Positions. | Yamamoto, Y., et al. 1996. Inorg Chem. 35: 2329-2336. PMID: 11666432
- Gold(i) and gold(iii) phosphine complexes: synthesis, anticancer activities towards 2D and 3D cancer models, and apoptosis inducing properties. | Srinivasa Reddy, T., et al. 2018. Dalton Trans. 47: 15312-15323. PMID: 30187047
- Chiral lanthanide lumino-glass for a circularly polarized light security device. | Kitagawa, Y., et al. 2020. Commun Chem. 3: 119. PMID: 36703364
- Reactions of tris(2,6-dimethoxyphenyl)phosphine with epoxides | Masanoir Wada and Aki Tsuboi . 1987. J. Chem. Soc., Perkin Trans. 1: 151-154.
- Liquid-liquid extraction of metal ions with tris (2,6-dimethoxyphenyl) phosphine and its quaternary phosphonium salts | Yuko Yamashoji, Takayuki Matsushita, Takahiro Kawaguchi, Minoru Tanaka, Toshiyuki Shono, Masanori Wada. 1990. Analytica Chimica Acta. 231: 107-113.
- Arene ruthenium(II) complexes coordinated by phosphino and two phenoxide groups in tris(2,6-dimethoxyphenyl)phosphine: crystal structure of (η6-1,2,3,4-Me4C6H2)Ru[P[lcub]2,6-(MeO)2C6H3[rcub] [lcub]2-O-6-MeOC6H3[rcub;]2] | Yasuhiro Yamamoto, Ryoichi Sato, Mayumi Ohshima, Fumiko Matsuo, Chihiro Sudoh. 1995. Journal of Organometallic Chemistry. 489: C68-C70.
- Reactions of tris(2,6-dimethoxyphenyl)arsine, tris(2,6-dimethoxyphenyl)stibine and tris(2,6-dimethoxyphenyl)bismuthine and their derivatives | Masanori Wada, Shin-ichi Miyake, Shinji Hayashi, Hiroshi Ohba, Shin-ichi Nobuki, Shuichi Hayase, Tatsuo Erabi. 1996. Journal of Organometallic Chemistry. 507: 53-63.
- Reaction of [RuCl2(DMSO)4] with aromatic phosphines bearing ortho-methoxy groups† | Yasuhiro Yamamoto, Ken-ichiro Sugawara, Tsuyoshi Aiko and Jian-Fang Ma. 1999. J. Chem. Soc., Dalton Trans. 4003-4008.
- Reactions of palladium complex of N,N-dimethylbenzylamine with aromatic phosphines bearing the methoxy groups at the 2,6-positions | Jian-Fang Ma 1, Yasushi Kojima, Yasuhiro Yamamoto. 2000. Journal of Organometallic Chemistry. 616: 149-156.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Tris(2,6-dimethoxyphenyl)phosphine, 5 g | sc-237379 | 5 g | $88.00 |