Molecular structure of Tris(2,4,6-trimethoxyphenyl)phosphine, CAS Number: 91608-15-0
Tris(2,4,6-trimethoxyphenyl)phosphine (CAS 91608-15-0)
Alternate Names:
TTMPP
Application:
Tris(2,4,6-trimethoxyphenyl)phosphine is a highly basic arylphosphine
CAS Number:
91608-15-0
Purity:
≥97%
Molecular Weight:
532.52
Molecular Formula:
C27H33O9P
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
Tris(2,4,6-trimethoxyphenyl)phosphine is a highly basic arylphosphine. Tris(2,4,6-trimethoxyphenyl)phosphine is a specialized organophosphorus compound characterized by its unique structure, consisting of a central phosphorus atom covalently bonded to three 2,4,6-trimethoxyphenyl groups. This molecular architecture imparts remarkable electronic and steric properties, making it an invaluable ligand in the realm of homogeneous catalysis. Its utility lies primarily in its ability to stabilize various metal catalysts through the formation of robust phosphine-metal complexes, facilitating a wide range of catalytic reactions, including cross-coupling reactions, hydroformylation, and asymmetric synthesis.
Tris(2,4,6-trimethoxyphenyl)phosphine (CAS 91608-15-0) References
- Stille coupling of stereochemically defined alpha-sulfonamidoorganostannanes. | Kells, KW. and Chong, JM. 2004. J Am Chem Soc. 126: 15666-7. PMID: 15571388
- TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles. | Matsukawa, S. and Tsukamoto, K. 2009. Org Biomol Chem. 7: 3792-6. PMID: 19707684
- Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones. | Matsukawa, S., et al. 2009. Molecules. 14: 3353-9. PMID: 19783929
- Direct Pd-catalyzed cross-coupling of functionalized organoaluminum reagents. | Groll, K., et al. 2012. Angew Chem Int Ed Engl. 51: 11157-61. PMID: 23037856
- Methoxylation of Acyl Fluorides with Tris(2,4,6-trimethoxyphenyl)phosphine via C-OMe Bond Cleavage under Metal-Free Conditions. | Wang, X., et al. 2020. J Org Chem. 85: 7526-7533. PMID: 32351110
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Tris(2,4,6-trimethoxyphenyl)phosphine, 2 g | sc-255706 | 2 g | $91.00 |