Molecular structure of (Triphenylphosphoranylidene)ketene, CAS Number: 15596-07-3
(Triphenylphosphoranylidene)ketene (CAS 15596-07-3)
Alternate Names:
(Triphenylphosphoranylidene)ethenone, Bestmann ylide, Ketenylidene(triphenyl)phosphorane
CAS Number:
15596-07-3
Molecular Weight:
302.31
Molecular Formula:
C20H15OP
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
QUICK LINKS
Ordering Information
Description
Technical Information
Safety Information
SDS & Certificate of Analysis
Participates in a variety of reactions including cycloaddition, multi-component, and domino reactions. (Triphenylphosphoranylidene)ketene is employed as a reagent in organic synthesis and as a catalyst for polymerization reactions. Its applications extend to the synthesis of diverse organic compounds, including dyes and agrochemicals. It plays a vital role in the creation of a wide array of polymers, such as polystyrene and polyethylene, by participating in their synthesis. Moreover, its significance extends to the realm of coordination chemistry, as it serves as a key component in the synthesis of metal complexes, exemplified by cobalt and ruthenium complexes.
(Triphenylphosphoranylidene)ketene (CAS 15596-07-3) References
- Anhydrous TEMPO-H: reactions of a good hydrogen atom donor with low-valent carbon centres. | Giffin, NA., et al. 2011. Org Biomol Chem. 9: 3672-80. PMID: 21472176
- Preparation of conjugated dienoates with Bestmann ylide: Towards the synthesis of zampanolide and dactylolide using a facile linchpin approach. | Wang, J., et al. 2015. Beilstein J Org Chem. 11: 1815-22. PMID: 26664601
- Investigating Biogenetic Hypotheses of the Securinega Alkaloids: Enantioselective Total Syntheses of Secu'amamine E/ent-Virosine A and Bubbialine. | Wehlauch, R., et al. 2017. Org Lett. 19: 548-551. PMID: 28094969
- Phosphorus Ylide Based Functionalizations of Tetronic and Tetramic Acids | Rainer Schobert*, Matthias Dietrich, Gillian Mullen, Juan-Manuel Urbina-Gonzalez. 2006. Synthesis. 22: 3902-3914.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
(Triphenylphosphoranylidene)ketene, 1 g | sc-251387 | 1 g | $141.00 |