Date published: 2026-4-4

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Trimethylboroxine (CAS 823-96-1)

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Alternate Names:
2,4,6-Trimethyl-boroxin
CAS Number:
823-96-1
Purity:
99%
Molecular Weight:
125.53
Molecular Formula:
C3H9B3O3
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Trimethylboroxine (TMB) has gained widespread recognition as a versatile organic compound extensively employed in scientific research. Notably, Trimethylboroxine exhibits characteristics of being colorless, odorless, non-toxic, and soluble in water and alcohols. Furthermore, it boasts high stability, enabling long-term storage. Trimethylboroxine serves as a robust electron acceptor and exhibits oxidizing properties in biochemical reactions. It can also function as a catalyst in select chemical reactions. In biochemical processes, Trimethylboroxine acts as an electron acceptor, facilitating electron transfer from one molecule to another. This unique capability empowers Trimethylboroxine to catalyze biochemical reactions effectively.


Trimethylboroxine (CAS 823-96-1) References

  1. Doping control for beta-adrenergic compounds through hair analysis.  |  Kintz, P., et al. 2000. J Forensic Sci. 45: 170-4. PMID: 10641933
  2. Design and Synthesis of Potent and Selective PIM Kinase Inhibitors by Targeting Unique Structure of ATP-Binding Pocket.  |  Nakano, H., et al. 2017. ACS Med Chem Lett. 8: 504-509. PMID: 28523101
  3. Spectroscopic Studies of Synthetic Methylaluminoxane: Structure of Methylaluminoxane Activators.  |  Joshi, A., et al. 2021. Chemistry. 27: 8753-8763. PMID: 33780574
  4. A methylation platform of unconventional inert aryl electrophiles: trimethylboroxine as a universal methylating reagent.  |  Feng, B., et al. 2020. Chem Sci. 11: 6031-6035. PMID: 34094095
  5. Rhoda-Electrocatalyzed C-H Methylation and Paired Electrocatalyzed C-H Ethylation and Propylation.  |  Kuciński, K., et al. 2022. Chemistry. 28: e202103837. PMID: 34714563
  6. Carba Analogues of Flupirtine and Retigabine with Improved Oxidation Resistance and Reduced Risk of Quinoid Metabolite Formation.  |  Wurm, KW., et al. 2022. ChemMedChem. 17: e202200262. PMID: 35687532
  7. Palladium-catalyzed nucleomethylation of alkynes for synthesis of methylated heteroaromatic compounds.  |  Yang, X., et al. 2022. Chem Sci. 13: 10095-10102. PMID: 36128232
  8. Electrolyte solution for the improved cycling performance of LiCoPO4/C composite cathodes  |  R Sharabi, E Markevich, K Fridman… - Electrochemistry …, 2013 - Elsevier. March 2013,. Electrochemistry Communications. Volume 28,: Pages 20-23.
  9. Polarizability and magnetizability anisotropies of trimethylboroxine, Me3B3O3.: Comparison of boroxine and benzene ring systems  |  DW Lamb, RI Keir, GLD Ritchie - Chemical physics letters, 1998 - Elsevier. 10 July 1998,. Chemical Physics Letters. Volume 291, Issues 1–2,: Pages 197-201.
  10. Improving cyclic stability of lithium cobalt oxide based lithium ion battery at high voltage by using trimethylboroxine as an electrolyte additive  |  X Wang, L Xing, X Liao, X Chen, W Huang, Q Yu… - Electrochimica …, 2015 - Elsevier. 10 August 2015,. Electrochimica Acta. Volume 173,: Pages 804-811.
  11. Enhanced high voltage performances of layered lithium nickel cobalt manganese oxide cathode by using trimethylboroxine as electrolyte additive  |  Q Yu, Z Chen, L Xing, D Chen, H Rong, Q Liu, W Li - Electrochimica Acta, 2015 - Elsevier. 10 September 2015,. Electrochimica Acta. Volume 176,: Pages 919-925.
  12. Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine  |  T Nishimura, A Ashouri, Y Ebe, Y Maeda… - Tetrahedron …, 2012 - Elsevier. 15 May 2012,. Tetrahedron: Asymmetry. Volume 23, Issue 9,: Pages 655-658.
  13. On the aromaticity of trimethylboroxine: A photoelectron spectroscopic study  |  I Novak, B Kovač - Chemical physics letters, 2007 - Elsevier., 25 May 2007,. Chemical Physics Letters. Volume 440, Issues 1–3: Pages 70-72.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Trimethylboroxine, 1 g

sc-253764
1 g
$42.00

Trimethylboroxine, 5 g

sc-253764A
5 g
$131.00