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Triethyl(silane-d) (CAS 1631-33-0)

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Alternate Names:
Deuterated triethylsilane
Application:
Triethyl(silane-d) is a deuterium labeled reagent for the hydrosilation of olefins
CAS Number:
1631-33-0
Purity:
≥98%
Molecular Weight:
117.28
Molecular Formula:
C6H15DSi
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Triethyl(silane-d) is a deuterated compound that is frequently used in research applications involving nuclear magnetic resonance (NMR) spectroscopy. As a deuterated solvent, it provides an environment with minimal NMR background signals, allowing for clearer observation of the chemical shifts and structural features of other molecules under study. Researchers also use Triethyl(silane-d) in the study of reaction mechanisms, particularly those involving silicon-based reagents, due to its relatively stable Si-C bonds and its ability to act as a reducing agent or a source of hydride ions. In addition, it serves as an internal standard or reference compound in NMR spectroscopy because of its well-defined resonance peaks. The compound is also part of investigations into organosilicon chemistry, where it is used to explore the properties and reactivities of silicon-containing compounds.


Triethyl(silane-d) (CAS 1631-33-0) References

  1. Simple synthesis of deuterium and 13C labeled trifluoromethyl phenyldiazirine derivatives as stable isotope tags for mass spectrometry.  |  Hashimoto, M. and Hatanaka, Y. 2004. Chem Pharm Bull (Tokyo). 52: 1385-6. PMID: 15516771
  2. An improved synthesis of cis-4-phenyl-2-propionamidotetralin (4-P-PDOT): a selective MT(2) melatonin receptor antagonist.  |  Lucarini, S., et al. 2008. Org Biomol Chem. 6: 147-50. PMID: 18075659
  3. Stereoselective hydrosilylation of enals and enones catalysed by palladium nanoparticles.  |  Benohoud, M., et al. 2011. Chemistry. 17: 8404-13. PMID: 21744402
  4. Tandem deuteration/hydrosilylation reactions catalyzed by a rhodium carbene complex under solvent-free conditions.  |  Egbert, JD. and Nolan, SP. 2012. Chem Commun (Camb). 48: 2794-6. PMID: 22297569
  5. Design, synthesis, and biological evaluation of deuterated C-aryl glycoside as a potent and long-acting renal sodium-dependent glucose cotransporter 2 inhibitor for the treatment of type 2 diabetes.  |  Xu, G., et al. 2014. J Med Chem. 57: 1236-51. PMID: 24456245
  6. The influence of acceptor nucleophilicity on the glycosylation reaction mechanism.  |  van der Vorm, S., et al. 2017. Chem Sci. 8: 1867-1875. PMID: 28553477
  7. Bent Bond/Antiperiplanar Hypothesis: Modulating the Reactivity and the Selectivity in the Glycosylation of Bicyclic Pyranoside Models.  |  Parent, JF., et al. 2020. J Org Chem. 85: 4220-4236. PMID: 32068401
  8. Diastereo- and enantioselective rhodium(III)-catalyzed reductive cyclization of cyclohexadienone-containing 1,6-dienes.  |  Tan, YX., et al. 2021. Chem Commun (Camb). 57: 9724-9727. PMID: 34474456
  9. A general synthesis of azetidines by copper-catalysed photoinduced anti-Baldwin radical cyclization of ynamides.  |  Jacob, C., et al. 2022. Nat Commun. 13: 560. PMID: 35091551
  10. Uncanonical Semireduction of Quinolines and Isoquinolines via Regioselective HAT-Promoted Hydrosilylation.  |  Hu, C., et al. 2023. J Am Chem Soc. 145: 25-31. PMID: 36548026
  11. Synthesis of vinyl-substituted alcohols using acetylene as a C2 building block.  |  Lin, Z., et al. 2023. Chem Sci. 14: 1912-1918. PMID: 36819868

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Triethyl(silane-d), 500 mg

sc-258292
500 mg
$479.00

What is the refractive index?

Asked by: SCchem16
Thank you for your question. This chemical, Triethyl(silane-d) (CAS 1631-33-0), has a refractive index of n20/D 1.4117.
Answered by: Chemical Support 2
Date published: 2017-03-24

What is this product soluble in?

Asked by: chemicalsmg
Thank you for your question. This chemical is soluble in chloroform and ethyl acetate. Please contact Technical Service if you have further questions concerning this product.
Answered by: Tech Service 9
Date published: 2017-07-14
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Rated 5 out of 5 by from Various publications cite the use of Triethyl(silane-d) to track the hydrosilation of olefins. -SCBT Publication Review
Date published: 2015-03-09
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Triethyl(silane-d) is rated 5.0 out of 5 by 1.
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