Date published: 2025-10-18

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Triallyl phosphite (CAS 102-84-1)

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CAS Number:
102-84-1
Molecular Weight:
202.19
Molecular Formula:
C9H15O3P
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Triallyl phosphite (TAP) stands as an organic compound of significant importance within the chemical industry, finding extensive use as a stabilizer, crosslinking agent, and flame retardant. Presenting as a colorless liquid with a pungent odor and a molecular formula of C9H15O3P, Triallyl phosphite embodies a versatile nature, granting it numerous applications across various domains such as polymer chemistry and agriculture. The scientific research community has conducted extensive studies on the diverse applications of triallyl phosphite. In polymer chemistry, it serves as a crosslinking agent, enhancing the mechanical properties of polymers. Additionally, triallyl phosphite has been employed as a flame retardant, effectively safeguarding textiles and plastics against combustion. Although the exact mechanism of action for triallyl phosphite remains incompletely understood, it is hypothesized to function as a crosslinking agent by forming covalent bonds between polymer chains. Moreover, triallyl phosphite acts as a flame retardant by liberating phosphorus-containing compounds that impede the combustion process. By further exploring the properties, applications, and mechanisms underlying triallyl phosphite, we can deepen our understanding of its versatile nature and its potential for advancing various scientific fields.


Triallyl phosphite (CAS 102-84-1) References

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  2. Regulation of Cathode-Electrolyte Interphase via Electrolyte Additives in Lithium Ion Batteries.  |  Wang, XT., et al. 2020. Chem Asian J. 15: 2803-2814. PMID: 32543733
  3. The synthesis of esters of phosphinic acids containing heterocyclic radicals: Communication 7. Esters of phosphinic acid with mono-and di-oxidoquinoxalinic radicals  |  Arbuzov, B. A., Zoroastrova, V. M., & Antokhina, L. A. 1961. Bulletin of the Academy of Sciences of the USSR, Division of chemical science. 10: 940-944.
  4. Displacement of alkyl groups from organophosphorus compounds studied by electron spin resonance  |  Kochi, J. K., & Krusic, P. J. 1969. Journal of the American Chemical Society. 91(14): 3944-3946.
  5. Chiral, non-racemic α-hydroxyphosphonates and phosphonic acids via stereoselective hydroxylation of diallyl benzylphosphonates  |  Skropeta, D., & Schmidt, R. R. 2003. Tetrahedron: Asymmetry. 14(2): 265-273.
  6. A convenient method for phosphorylation using triallyl phosphite  |  Li, S. Z., Ahmar, M., Queneau, Y., & Soulère, L. 2015. Tetrahedron letters. 56(32): 4694-4696.
  7. The application of mycelial wastes from microbiological production of antibacterial antibiotics as lubricating oil additives  |  , et al. 2016. Russian Journal of General Chemistry. 86: 2929–2932.
  8. Triallyl phosphite as an electrolyte additive to improve performance at elevated temperature of LiNi0. 6Co0. 2Mn0. 2O2/graphite cells  |  Lin, Y., Zhang, H., Yue, X., Yu, L., & Fan, W. 2019. Journal of Electroanalytical Chemistry. 832: 408-416.
  9. Synthesis of polycyclic phosphonates via an intramolecular Diels-Alder reaction of 2-benzoylbenzalaldehyde and alkenyl phosphites  |  Yamana, K., & Nakano, H. 2019. Heterocyclic Communications. 25(1): 73-77https://www.degruyter.com/document/doi/10.1515/hc-2019-0011/html.
  10. Electrolyte additives for improved lithium-ion battery performance and overcharge protection  |  van Ree, T. 2020. Current Opinion in Electrochemistry. 21: 22-30.
  11. Study on boron-containing electrolytes at extra-high temperatures for lithium-ion batteries  |  Yang, L., Wang, P., Zhao, D., Wei, Y., Han, Y., Zeng, S.,.. & Li, S. 2020. Sustainable Energy & Fuels. 4(8): 4126-4136.
  12. Improving High‐Voltage Performance of a LiNi0. 5Co0. 2Mn0. 3O2 Cathode with Triallyl Phosphite as an Electrolyte Additive  |  Fan, S., Sun, M., Liu, Y., & Wang, Q. 2021. ChemElectroChem. 8(23): 4580-4588.
  13. Highly reinforce the interface stability using 2-Phenyl-1H-imidazole-1-sulfonate electrolyte additive to enhance the high temperature performance of LiNi0. 8Co0. 1Mn0. 1O2/graphite batteries  |  He, X., Li, Y., Wang, W., Zeng, X., Hu, H., Li, H.,.. & Nan, J. 2023. Journal of Energy Chemistry. 80: 10-22.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Triallyl phosphite, 10 g

sc-272709
10 g
$78.00