Molecular structure of Tetrakis(triphenylphosphine)palladium(0), CAS Number: 14221-01-3
Tetrakis(triphenylphosphine)palladium(0) (CAS 14221-01-3)
Alternate Names:
Palladium-tetrakis(triphenylphosphine)
Application:
Tetrakis(triphenylphosphine)palladium(0) is a high-yielding catalyst used in coupling reactions
CAS Number:
14221-01-3
Purity:
≥98%
Molecular Weight:
1155.56
Molecular Formula:
C72H60P4Pd
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
QUICK LINKS
Ordering Information
Description
Technical Information
Safety Information
SDS & Certificate of Analysis
Tetrakis(triphenylphosphine)palladium(0) is a high-yielding catalyst used in coupling reactions and reductive debromination of fused diporphyrins. It is also used in the synthesis of chlorins and porphodimethenes with alkyllithiums. It is particularly exploited in cross-coupling reactions, such as the Suzuki-Miyaura, Stille, and Heck reactions, among others. These reactions are for constructing the carbon skeletons of organic molecules, including agrochemicals and materials science precursors. By exchanging one or more triphenylphosphine ligands with other ligands, chemists can tailor the reactivity and selectivity of the palladium catalyst for specific reactions or substrates.
Tetrakis(triphenylphosphine)palladium(0) (CAS 14221-01-3) References
- Synthesis, Characterization, and Theoretical Investigation of Two-Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-Accepting Carbenes. | Roy, S., et al. 2015. Chemistry. 21: 9312-8. PMID: 25940809
- Morita-Baylis-Hillman Reaction of α,β-Unsaturated Ketones with Allylic Acetates by the Combination of Transition-Metal Catalysis and Organomediation. | Li, YQ., et al. 2016. J Org Chem. 81: 4429-33. PMID: 27186906
- A Ligand-Enabled Palladium-Catalyzed Highly para-Selective Difluoromethylation of Aromatic Ketones. | Tu, G., et al. 2018. Angew Chem Int Ed Engl. 57: 15597-15601. PMID: 30299562
- Palladium(0)-assisted synthesis of C-glycopyranosyl compounds. | Dunkerton, LV., et al. 1987. Carbohydr Res. 171: 89-107. PMID: 3442778
- Preparation of tricationic tris(pyridylpalladium(II)) metallacyclophane as an anion receptor. | Danjo, H., et al. 2022. Chem Commun (Camb). 58: 2196-2199. PMID: 35072179
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Tetrakis(triphenylphosphine)palladium(0), 1 g | sc-253678 | 1 g | $57.00 | |||
Tetrakis(triphenylphosphine)palladium(0), 5 g | sc-253678A | 5 g | $228.00 |