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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate (CAS 21797-13-7)

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Alternate Names:
NSC 307191; Palladium(II) tetrafluoroborate tetraacetonitrile complex
Application:
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a precursor for synthesis of dendritic SCS-pincer palladium complexes
CAS Number:
21797-13-7
Purity:
≥98%
Molecular Weight:
444.24
Molecular Formula:
C8H12B2F8N4Pd
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a coordination complex that serves as a catalyst in various organic synthesis reactions. Its mechanism of action involves the coordination of the palladium center with the acetonitrile ligands, forming a stable complex that can undergo oxidative addition and reductive elimination reactions. This complex is particularly useful in cross-coupling reactions, such as the Suzuki-Miyaura and Heck reactions, where it facilitates the formation of carbon-carbon bonds. Tetrakis(acetonitrile)palladium(II) tetrafluoroborate acts as a versatile catalyst due to its ability to undergo multiple catalytic cycles, enabling the efficient and selective formation of complex organic molecules.


Tetrakis(acetonitrile)palladium(II) tetrafluoroborate (CAS 21797-13-7) References

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  3. Self-assembled supramolecular cages containing ruthenium(II) polypyridyl complexes.  |  Yang, J., et al. 2015. Chem Commun (Camb). 51: 4465-8. PMID: 25679952
  4. Super-secondary structure peptidomimetics: design and synthesis of an α-α hairpin analogue.  |  Nevola, L., et al. 2013. Supramol Chem. 25: 586-590. PMID: 26052191
  5. Growth of polystyrene films via gas-phase polymerization with [Pd(CH3CN)4][BF4]2 thin film catalyst  |  Kimberly S. Wain, Ayusman Sen, Seong Han Kim. 2005. Journal of Polymer Science Part A: Polymer Chemistry. 43: 1930-1934.
  6. Successive coordination of palladium(II)-ions and terpyridine-ligands to a pyridyl-terminated self-assembled monolayer on gold  |  Johannes Poppenberg a, Sebastian Richter a, Erik Darlatt b, Christoph H.-H. Traulsen a, Hyegeun Min b, Wolfgang E.S. Unger b, Christoph A. Schalley a. 2012. Surface Science. 606: 367-377.
  7. Asymmetric α-hydroxy ketone synthesis by direct ketone oxidation using a bimetallic palladium(II) complex  |  Othman A. Hamed a, Arab El-Qisairi b, Hanan Qaseer b, Emad M. Hamed c †, Patrick M. Henry d ✠, Daniel P. Becker d. 2012. Tetrahedron Letters. 53: 2699-2701.
  8. Palladium(II)-catalyzed asymmetric cycloisomerization of enynes for axially chiral biaryl construction  |  Nobuaki Kadoya, Masato Murai, Masako Ishiguro, Jun'ichi Uenishi, Motokazu Uemura. 2013. Tetrahedron Letters. 54: 512-514.
  9. Tris(acetonitrile)chloropalladium tetrafluoroborate synthesis, application and structural analysis  |  Izabela Dybała, Oleg M. Demchuk. 2016. Journal of Molecular Structure. 1121: 135-141.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, 250 mg

sc-229427
250 mg
$68.00