Date published: 2025-12-5

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Tetrafluoroterephthalonitrile (CAS 1835-49-0)

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Alternate Names:
Perfluoroterephthalonitrile
Application:
Tetrafluoroterephthalonitrile is a synthessi reagent primarily used to create polymers of intinsic microporosity
CAS Number:
1835-49-0
Purity:
≥98%
Molecular Weight:
200.09
Molecular Formula:
C8F4N2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Tetrafluoroterephthalonitrile is a fluorinated compound with a unique structure that can react with alkyl grignard reagents to form 4-alkyltetraflurorobenzonitriles. It acts as a four electron donor ligand. Tetrafluoroterephthalonitrile can be used to synthesize polymers of intrinsic microporosity. It has been used to study UV rearranged polymers of teh PIM-1 type membrane for the efficient separation of H2 and CO2.


Tetrafluoroterephthalonitrile (CAS 1835-49-0) References

  1. Simultaneous variation of multipole parameters and Gram-Charlier coefficients in a charge-density study of tetrafluoroterephthalonitrile based on X-ray and neutron data.  |  Sørensen, HO., et al. 2003. Acta Crystallogr A. 59: 540-50. PMID: 14581753
  2. Allergic contact dermatitis from tetrafluoroterephthalonitrile and TFX diamine.  |  Carmichael, AJ., et al. 1989. Contact Dermatitis. 20: 233-4. PMID: 2524357
  3. A Facile Cyclization Method Improves Peptide Serum Stability and Confers Intrinsic Fluorescence.  |  Ngambenjawong, C., et al. 2017. Chembiochem. 18: 2395-2398. PMID: 29044914
  4. Tetrafluoroterephthalonitrile-crosslinked β-cyclodextrin polymers for efficient extraction and recovery of organic micropollutants from water.  |  Li, C., et al. 2018. J Chromatogr A. 1541: 52-56. PMID: 29433822
  5. Synthesis and Characterization of Liquid-Crystalline Tetraoxapentacene Derivatives Exhibiting Aggregation-Induced Emission.  |  Hiscock, LK., et al. 2019. Chemistry. 25: 1018-1028. PMID: 30335207
  6. Reduction of a Tetrafluoroterephthalonitrile-β-Cyclodextrin Polymer to Remove Anionic Micropollutants and Perfluorinated Alkyl Substances from Water.  |  Klemes, MJ., et al. 2019. Angew Chem Int Ed Engl. 58: 12049-12053. PMID: 31210007
  7. Synthesis of Emissive Heteroacene Derivatives via Nucleophilic Aromatic Substitution.  |  Hiscock, LK., et al. 2019. J Org Chem. 84: 15530-15537. PMID: 31651162
  8. Tetrafluoroterephthalonitrile-crosslinked β-cyclodextrin polymer as a binding agent of diffusive gradients in thin-films for sampling endocrine disrupting chemicals in water.  |  Li, H., et al. 2021. Chemosphere. 280: 130774. PMID: 33971412
  9. Highly Perfluorinated Covalent Triazine Frameworks Derived from a Low-Temperature Ionothermal Approach Towards Enhanced CO2 Electroreduction.  |  Suo, X., et al. 2021. Angew Chem Int Ed Engl. 60: 25688-25694. PMID: 34582075
  10. Porous multifunctional phenylcarbamoylated-β-cyclodextrin polymers for rapid removal of aromatic organic pollutants.  |  Wang, H., et al. 2022. Environ Sci Pollut Res Int. 29: 13893-13904. PMID: 34599452
  11. Supramolecular tessellations by the exo-wall interactions of pagoda[4]arene.  |  Han, XN., et al. 2021. Nat Commun. 12: 6378. PMID: 34737290
  12. Synthesis of reusable cyclodextrin polymers for removal of naphthol and naphthylamine from water.  |  Xu, W., et al. 2022. Environ Sci Pollut Res Int. 29: 22106-22121. PMID: 34778912
  13. BODIPY-Based Polymers of Intrinsic Microporosity for the Photocatalytic Detoxification of a Chemical Threat.  |  Atilgan, A., et al. 2022. ACS Appl Mater Interfaces. 14: 12596-12605. PMID: 35234435
  14. Construction of a magnetic solid-phase extraction method for the analysis of azole pesticides residue in medicinal plants.  |  Senosy, IA., et al. 2022. Food Chem. 386: 132743. PMID: 35364494

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Tetrafluoroterephthalonitrile, 5 g

sc-229414
5 g
$31.00