Date published: 2025-10-15

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Silver(I) oxide (CAS 20667-12-3)

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Alternate Names:
Argentous oxide; Disilver oxide
Application:
Silver(I) oxide is a monoprotection mediator of symmetrical diols
CAS Number:
20667-12-3
Molecular Weight:
231.74
Molecular Formula:
Ag2O
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Silver(I) oxide serves as a potent oxidizing agent, playing a role in facilitating redox reactions within experimental frameworks. As it accepts electrons from a diverse array of substances, it catalyzes their oxidation, leading to significant alterations in their chemical structures. This ability to transfer oxygen atoms to other compounds makes Silver(I) oxide indispensable in the synthesis and modification of both organic and inorganic molecules. Its interaction with other substances at the molecular level, through the donation of oxygen, results in the creation of novel chemical bonds and structures, for the development of new materials and chemicals. Silver(I) oxide′s participation in these reactions does more than merely push them forward; it actively shapes the path and outcomes of these transformations.


Silver(I) oxide (CAS 20667-12-3) References

  1. Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride.  |  Mori, A., et al. 2000. Org Lett. 2: 2935-7. PMID: 10986076
  2. Palladium-catalyzed cross-coupling of silanols, silanediols, and silanetriols promoted by silver(I) oxide.  |  Hirabayashi, K., et al. 2000. J Org Chem. 65: 5342-9. PMID: 10993364
  3. Silver(I) oxide mediated highly selective monotosylation of symmetrical diols. Application to the synthesis of polysubstituted cyclic ethers.  |  Bouzide, A. and Sauvé, G. 2002. Org Lett. 4: 2329-32. PMID: 12098239
  4. Formation of water-soluble pincer silver(I)-carbene complexes: a novel antimicrobial agent.  |  Melaiye, A., et al. 2004. J Med Chem. 47: 973-7. PMID: 14761198
  5. Silver(I) oxide mediated selective monoprotection of diols in pyranosides.  |  Wang, H., et al. 2004. J Org Chem. 69: 5774-7. PMID: 15307757
  6. Shape- and size-selective electrochemical synthesis of dispersed silver(I) oxide colloids.  |  Murray, BJ., et al. 2005. Nano Lett. 5: 2319-24. PMID: 16277476
  7. catena-Poly[3,3'-diethyl-1,1'-(propane-1,3-di-yl)di(1H-imidazol-3-ium) [silver(I)-di-μ-iodido-silver(I)-di-μ-iodido]].  |  Huo, JZ., et al. 2012. Acta Crystallogr Sect E Struct Rep Online. 68: m787. PMID: 22719338
  8. Cosolvent-Promoted O-Benzylation with Silver(I) Oxide: Synthesis of 1'-Benzylated Sucrose Derivatives, Mechanistic Studies, and Scope Investigation.  |  Wang, L., et al. 2016. J Org Chem. 81: 4464-74. PMID: 27149197
  9. Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(i) oxide.  |  Marr, AC., et al. 2019. Dalton Trans. 48: 1947-1949. PMID: 30637429
  10. A Highly Efficient Glycosidation of Glycosyl Chlorides by Using Cooperative Silver(I) Oxide-Triflic Acid Catalysis.  |  Geringer, SA., et al. 2020. Chemistry. 26: 8053-8063. PMID: 32145116
  11. Antiviral, Antibacterial, Antifungal, and Cytotoxic Silver(I) BioMOF Assembled from 1,3,5-Triaza-7-Phoshaadamantane and Pyromellitic Acid.  |  Jaros, SW., et al. 2020. Molecules. 25: PMID: 32369972
  12. Silver(I) Oxide-/DBU-Promoted Synthesis of Dihydrofuran Units through Allenyl Silver Formation.  |  Yu, B., et al. 2020. Chemistry. 26: 17455-17461. PMID: 32978998
  13. Application of mycogenic silver/silver oxide nanoparticles in electrochemical glucose sensing; alongside their catalytic and antimicrobial activity.  |  Islam, SN., et al. 2021. 3 Biotech. 11: 342. PMID: 34221813
  14. Cross-Link Density, Mechanical and Thermal Properties of Chloroprene Rubber Cross-Linked with Silver(I) Oxide.  |  Kobędza, P., et al. 2022. Materials (Basel). 15: PMID: 35329456

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Silver(I) oxide, 10 g

sc-253562
10 g
$93.00

Silver(I) oxide, 50 g

sc-253562A
50 g
$285.00