Molecular structure of Samarium(II) iodide, CAS Number: 32248-43-4
Samarium(II) iodide (CAS 32248-43-4)
CAS Number:
32248-43-4
Molecular Weight:
404.17
Molecular Formula:
SmI2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Samarium(II) iodide (SmI2) plays a role in the realm of organic chemistry, serving as a versatile reagent for various synthetic transformations. Extensive research has been conducted to unravel its properties and applications. Within scientific research, Samarium(II) iodide finds widespread utility in organic synthesis, enabling the creation of cyclic compounds, heterocycles, polymers, pharmaceuticals, agrochemicals, and other fine chemicals. Moreover, it contributes to the synthesis of materials employed in electronic and optical applications. Although the precise mechanism of action of Samarium(II) iodide remains partially elusive, it is believed that the samarium metal functions as a Lewis acid, while iodine acts as a Lewis base.
Samarium(II) iodide (CAS 32248-43-4) References
- Samarium(II) iodide promoted fragmentation and sequential reactions of aromatic 1,4-diketones. | Williams, DB., et al. 2000. J Org Chem. 65: 2834-6. PMID: 10808468
- Sequenced reactions with samarium(II) iodide. Sequential intramolecular Barbier cyclization/Grob fragmentation for the synthesis of medium-sized carbocycles. | Molander, GA., et al. 2001. J Org Chem. 66: 4511-6. PMID: 11421769
- Sequenced Reactions with Samarium(II) Iodide. Domino Epoxide Ring-Opening/Ketyl Olefin Coupling Reactions. | Molander, GA. and del Pozo Losada, C. 1997. J Org Chem. 62: 2935-2943. PMID: 11671657
- Conjugate Addition Reactions Mediated by Samarium(II) Iodide. | Molander, GA. and Harris, CR. 1997. J Org Chem. 62: 7418-7429. PMID: 11671859
- Sequential Ketyl-Olefin Coupling/beta-Elimination Reactions Mediated by Samarium(II) Iodide. | Molander, GA. and Harris, CR. 1998. J Org Chem. 63: 812-816. PMID: 11672078
- Sequenced reactions with samarium(II) iodide. Sequential intramolecular Reformatsky/nucleophilic acyl substitution reactions for the synthesis of medium-sized carbocycles. | Molander, GA., et al. 2002. J Org Chem. 67: 3459-63. PMID: 12003559
- Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones. | Molander, GA. and St Jean, DJ. 2002. J Org Chem. 67: 3861-5. PMID: 12027704
- Samarium(II)-mediated reactions of gamma,delta-unsaturated ketones. Cyclization and fragmentation processes. | Hutton, TK., et al. 2002. Org Lett. 4: 2345-7. PMID: 12098243
- Samarium(II) iodide mediated radical/polar crossover reactions of cyclobutenes. An efficient approach to the BCD ring system of the penitrems. | Rivkin, A., et al. 2003. Org Lett. 5: 419-22. PMID: 12583733
- Preparation of samarium(II) iodide: quantitative evaluation of the effect of water, oxygen, and peroxide content, preparative methods, and the activation of samarium metal. | Szostak, M., et al. 2012. J Org Chem. 77: 3049-59. PMID: 22375820
- Recent advances in the chemoselective reduction of functional groups mediated by samarium(II) iodide: a single electron transfer approach. | Szostak, M., et al. 2013. Chem Soc Rev. 42: 9155-83. PMID: 24013846
- Synthesis of Nitrogen Heterocycles Using Samarium(II) Iodide. | Shi, S. and Szostak, M. 2017. Molecules. 22: PMID: 29160806
- Complete denitrification of nitrate and nitrite to N2 gas by samarium(II) iodide. | Marks, WR., et al. 2020. Chem Commun (Camb). 56: 11441-11444. PMID: 32851391
- Samarium(ii) iodide-mediated reactions applied to natural product total synthesis. | Heravi, MM. and Nazari, A. 2022. RSC Adv. 12: 9944-9994. PMID: 35424959
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Samarium(II) iodide, 1 g | sc-253532 | 1 g | $181.00 |