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(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (CAS 133545-17-2)

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Alternate Names:
(S)-(−)-MeO-BIPHEP; SL-A101-2
Application:
CAS Number:
133545-17-2
Purity:
≥97%
Molecular Weight:
582.61
Molecular Formula:
C38H32O2P2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) is a compound that functions as a ligand in transition metal-catalyzed reactions. It may act as a chelating agent, coordinating with transition metal ions to form stable complexes. (S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-Diyl)Bis(Diphenylphosphine)′s mechanism of action involves binding to the metal center, facilitating various catalytic processes such as cross-coupling reactions, hydrogenation, and C-H activation. Through its coordination with transition metals, it may influence the reactivity and selectivity of these catalytic reactions, ultimately impacting the efficiency of the overall process. S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) may also participate in ligand exchange reactions, further modulating the behavior of the metal catalyst. In this way, the compound plays a functional role in controlling the outcome of synthetic transformations by influencing the behavior of transition metal complexes at the molecular level.


(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (CAS 133545-17-2) References

  1. Synthesis of (1S,3aS)-8-(2,3,3a,4,5, 6-hexahydro-1H-phenalen-1-yl)-1-phenyl-1,3,8-triaza-spiro[4. 5]decan-4-one, a potent and selective orphanin FQ (OFQ) receptor agonist with anxiolytic-like properties.  |  Wichmann, J., et al. 2000. Eur J Med Chem. 35: 839-51. PMID: 11006485
  2. Stereospecific Hydrogenolysis of Lactones: Application to the Total Syntheses of (R)-ar-Himachalene and (R)-Curcumene.  |  Spielmann, K., et al. 2017. J Org Chem. 82: 4737-4743. PMID: 28398050
  3. Axially dissymmetric diphosphines in the biphenyl series: synthesis of (6, 6′‐dimethoxybiphenyl‐2, 2′‐diyl) bis (diphenylphosphine)('MeO‐BIPHEP') and analogues via an ortho‐lithiation/iodination Ullmann‐reaction approach  |  Schmid, R., Foricher, J., Cereghetti, M., & Schönholzer, P. 1991. Helvetica chimica acta. 74(2): 370-389.
  4. Regio‐and stereoregular copolymerisation of propene with carbon monoxide catalysed by palladium complexes containing atropisomeric diphosphine ligands  |  Bronco, S., & Consiglio, G. 1996. Macromolecular Chemistry and Physics. 197(1): 355-365.
  5. Enantioselective alternating terpolymerization of propene and ethene with carbon monoxide  |  Sesto, B., Bronco, S., Gindro, E. L., & Consiglio, G. 2001. acromolecular Chemistry and Physics. 202(10): 2059-2064.
  6. Asymmetric one-pot reactions using heterogeneous chemical catalysis: recent steps towards sustainable processes  |  Szőllősi, G. 2018. Catalysis Science & Technology. 8(2): 389-422.
  7. Ni-catalyzed enantioconvergent coupling of epoxides with alkenylboronic acids: construction of oxindoles bearing quaternary carbons  |  Wu, L., Yang, G., & Zhang, W. 2020. CCS Chemistry. 2(2): 623-631.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine), 100 mg

sc-229169
100 mg
$74.00

(S)-(−)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine), 500 mg

sc-229169A
500 mg
$238.00