(S)-(−)-Cl-MeO-BIPHEP (CAS 185913-98-8)
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(S)-(−)-Cl-MeO-BIPHEP is a chiral phosphine ligand that can be used as a catalyst for asymmetric synthesis. It may act to be efficient and selective in catalytic reactions, with high yields and enantioselectivity. Asymmetric catalysis is a cornerstone of modern synthetic organic chemistry, especially in fine chemical industries, where the production of single enantiomers of molecules is often necessary due to the distinct biological activity of different enantiomers. The ligand′s application includes, but is not limited to, asymmetric hydrogenation reactions, where it can help in reducing a variety of substrates like ketones, imines, and unsaturated carbon-carbon bonds, producing chiral alcohols, amines, and other compounds with high enantioselectivity. (S)-(−)-Cl-MeO-BIPHEP catalyzes the allylation of various substituted styrenes, as well as the regiospecific formation of polyketides.
(S)-(−)-Cl-MeO-BIPHEP (CAS 185913-98-8) References
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- Rhodium-catalyzed cyclization of diynes with nitrones: a formal [2+2+5] approach to bridged eight-membered heterocycles. | Wang, C., et al. 2014. Angew Chem Int Ed Engl. 53: 11940-3. PMID: 25220662
- Copper-Catalyzed Diastereo- and Enantioselective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine | Gaku Hattori, Yoshihiro Miyake Dr., Yoshiaki Nishibayashi Prof. Dr. 2010. ChemCatChem. 2: 155-158.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
(S)-(−)-Cl-MeO-BIPHEP, 1 g | sc-236560 | 1 g | $709.00 |