Prop-1-ene-1,3-sultone (CAS 21806-61-1)
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Prop-1-ene-1,3-sultone is a cyclic sulfonic acid ester that is primarily used as a reactive intermediate in organic synthesis and polymer chemistry. It is used in the synthesis of polymers and as a cross-linking agent for various polymer systems. It can react with nucleophiles, such as amines or thiols, to form covalent bonds and introduce desired properties into polymers. It is also employed in the synthesis of electrolytes for lithium-ion batteries. It improves the stability and performance of the battery by enhancing the formation of a stable solid-electrolyte interphase (SEI) layer on the electrode surfaces. Furthermore, Prop-1-ene-1,3-sultone is used in bioconjugation chemistry to modify biomolecules, such as proteins or peptides. It can react selectively with nucleophilic amino acid residues, such as cysteine or histidine, to introduce specific functional groups or tags for various purposes, including protein labeling, bioconjugation, or immobilization. Lastly, Prop-1-ene-1,3-sultone is utilized in the synthesis of ion exchange resins for applications in water treatment, chromatography, or separation processes. It can introduce sulfonic acid groups into the resin structure, allowing for the selective binding and exchange of ions.
Prop-1-ene-1,3-sultone (CAS 21806-61-1) References
- Synthesis and Diels-Alder reactions of prop-1-ene-1, 3-sultone, and chemical transformations of the Diels-Alder adducts | Chan, W. H., & Lee, A. W. 1999. Tetrahedron. 55(8): 2245-2262.
- 1, 3-Dipolar cycloadditions of prop-1-ene-1, 3-sultone with nitrile oxides/nitrones | Zhang, H., Chan, W. H., Lee, A. W., & Wong, W. Y. 2003. Tetrahedron letters. 44(2): 395-397.
- 1, 3‐dipolar cycloaddition reactions of nitrile oxides to prop‐1‐ene‐1, 3‐sultone | Tian, L., Xu, G. Y., Ye, Y., & Liu, L. Z. 2003. Journal of heterocyclic chemistry. 40(6): 1071-1074.
- Prop-1-ene-1, 3-sultone as SEI formation additive in propylene carbonate-based electrolyte for lithium ion batteries | Li, B., Xu, M., Li, T., Li, W., & Hu, S. 2012. Electrochemistry Communications. 17: 92-95.
- Properties of solid electrolyte interphase formed by prop-1-ene-1, 3-sultone on graphite anode of Li-ion batteries | Li, B., Xu, M., Li, B., Liu, Y., Yang, L., Li, W., & Hu, S. 2013. Electrochimica Acta. 105: 1-6.
- The role of prop-1-ene-1, 3-sultone as an additive in lithium-ion cells | Self, J., Hall, D. S., Madec, L., & Dahn, J. R. 2015. Journal of Power Sources. 298: 369-378.
- Understanding the role of prop-1-ene-1, 3-sultone and vinylene carbonate in LiNi1/3Mn1/3Co1/3O2/graphite pouch cells: electrochemical, GC-MS and XPS analysis. | Madec, L., Petibon, R., Xia, J., Sun, J. P., Hill, I. G., & Dahn, L. R. 2015. Journal of The Electrochemical Society. 162(14): A2635.
- Study of the consumption of the additive prop-1-ene-1, 3-sultone in Li [Ni0. 33Mn0. 33Co0. 33] O2/graphite pouch cells and evidence of positive-negative electrode interaction | Petibon, R., Madec, L., Rotermund, L. M., & Dahn, J. R. 2016. Journal of Power Sources. 313: 152-163.
- Reductive decomposition mechanism of Prop-1-ene-1, 3-sultone in the formation of a solid–electrolyte interphase on the anode of a lithium-ion battery | Han, Y. K., Yoo, J., & Jung, J. 2016. The Journal of Physical Chemistry C. 120(50): 28390-28397.
- A study of vinylene carbonate and prop-1-ene-1, 3 sultone electrolyte additives using polycrystalline Li [Ni0. 6Mn0. 2Co0. 2] O2 in positive/positive symmetric cells | Liu, Y., Hamam, I., & Dahn, J. R. 2020. Journal of The Electrochemical Society. 167(11): 110527.
- Comparative study of 1, 3-propane sultone, prop-1-ene-1, 3-sultone and ethylene sulfate as film-forming additives for sodium ion batteries | Zhang, Q., Wang, Z., Li, X., Guo, H., Peng, W., Wang, J., & Yan, G. 2022. Journal of Power Sources. 541: 231726.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Prop-1-ene-1,3-sultone, 1 g | sc-482257 | 1 g | $275.00 |