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Phenylmagnesium bromide solution (CAS 100-58-3)

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Application:
Phenylmagnesium bromide solution is a brominated organometaliic compound for proteomics research
CAS Number:
100-58-3
Molecular Weight:
181.31
Molecular Formula:
C6H5MgBr
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Phenyl-magnesium bromide solution can be used as a pesticide. This particular compound reacts with ester hydrochloride in the presence of an organic base. This interaction generates a reactive intermediate, which subsequently participates in transfer reactions with various other organic compounds.


Phenylmagnesium bromide solution (CAS 100-58-3) References

  1. Reactivity of iron verdohemes with phenylmagnesium bromide. Formation of paramagnetic iron-phenyl complexes.  |  Lord, PA., et al. 2002. Inorg Chem. 41: 1011-4. PMID: 11849107
  2. STUDIES ON QUINOLIZINIUM SALTS. 3. RING OPENING REACTIONS OF MONOMETHYLQUINOLIZINIUM BROMIDES BY PHENYLMAGNESIUM BROMIDE.  |  MIYADERA, T. 1965. Chem Pharm Bull (Tokyo). 13: 503-10. PMID: 14294848
  3. Kinetics of the grignard reaction with silanes in diethyl ether and ether-toluene mixtures.  |  Tuulmets, A., et al. 2003. J Org Chem. 68: 9933-7. PMID: 14682685
  4. The reaction of beta-cyclohexanedione (dihydroresorcinol) and its ethyl enol ether with phenylmagnesium bromide.  |  WOODS, GF. and TUCKER, IW. 1948. J Am Chem Soc. 70: 2174-7. PMID: 18863814
  5. Site-isolation and recycling of PdCl(2) using PDMS thimbles.  |  Miller, AL. and Bowden, NB. 2009. J Org Chem. 74: 4834-40. PMID: 19558181
  6. The reaction of phenylmagnesium bromide with 2-chloro-4-methylcyclohexanone.  |  NEWMAN, MS. and BOOTH, WT. 1947. J Org Chem. 12: 737-9. PMID: 20264599
  7. Phenyl derivative of iron 5,10,15-tritolylcorrole.  |  Nardis, S., et al. 2014. Inorg Chem. 53: 4215-27. PMID: 24697623
  8. Pentafluorosulfanyldifluoroacetic acid: rebirth of a promising building block.  |  Matsnev, AV., et al. 2014. Org Lett. 16: 2402-5. PMID: 24724944
  9. meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and a Stable meso-Oxy Radical.  |  Shimizu, D., et al. 2015. Angew Chem Int Ed Engl. 54: 6613-7. PMID: 25864562
  10. Pyreniporphyrins: Porphyrin Analogues That Incorporate a Polycyclic Aromatic Hydrocarbon Subunit within the Macrocyclic Framework.  |  Gao, R., et al. 2017. J Org Chem. 82: 6680-6688. PMID: 28574261
  11. Radiosynthesis of 1-iodo-2-[11 C]methylpropane and 2-methyl-1-[11 C]propanol and its application for alkylation reactions and C-C bond formation.  |  Rotteveel, L., et al. 2017. J Labelled Comp Radiopharm. 60: 566-576. PMID: 28755455
  12. N-Heterocyclic carbene-chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic bromides.  |  Tang, J., et al. 2018. Chem Commun (Camb). 54: 9325-9328. PMID: 30073225
  13. Novel analgesics and molecular rearrangements in the morphine-thebaine group. XX. Reaction of 7-beta-cyano-6,14-endo-etheno-7-alpha-methyl-6,7,8,14-tetrahydrothebaine with phenylmagnesium bromide.  |  Lewis, JW. and Readhead, MJ. 1971. J Chem Soc Perkin 1. 6: 1161-3. PMID: 5102745
  14. Synthesis of DL-[3-11C]phenylalanine.  |  Kilbourn, MR., et al. 1984. Int J Appl Radiat Isot. 35: 603-5. PMID: 6469391
  15. Synthesis, conformational analysis, and antiarrhythmic properties of 7-benzyl-3-thia-7-azabicyclo[3.3.1]nonan-9-one, 7-benzyl-3-thia-7-azabicyclo[3.3.1]nonane hydroperchlorate, and 7-benzyl-9-phenyl-3-thia-7-azabicyclo[3.3.1]nonan-9-ol hydroperchlorate and derivatives: single-crystal X-ray diffraction analysis and evidence for chair-chair and chair-boat conformers in the solid state.  |  Bailey, BR., et al. 1984. J Med Chem. 27: 758-67. PMID: 6737418

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Phenylmagnesium bromide solution, 100 ml

sc-362064
100 ml
$71.00

Phenylmagnesium bromide solution, 800 ml

sc-362064A
800 ml
$177.00