Pentafluorophenol (CAS 771-61-9)
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Pentafluorophenol is a compound that functions as a strong acid in various chemical reactions. It is used as a catalyst in the synthesis of agrochemicals, and other organic compounds. Pentafluorophenol′s mechanism of action involves its ability to donate a proton, facilitating the formation of new chemical bonds and promoting the rearrangement of molecular structures. Pentafluorophenol is particularly effective in activating nucleophiles and promoting substitution reactions, making it useful in the development of novel chemical compounds. Its high reactivity and ability to facilitate complex chemical transformations make it a useful reagent in development of new materials and compounds. Pentafluorophenol′s mechanism of action involves its interaction with specific functional groups, enabling the modification of organic molecules and the synthesis of diverse chemical entities.
Pentafluorophenol (CAS 771-61-9) References
- Trichlorophenol (TCP) sulfonate esters: a selective alternative to pentafluorophenol (PFP) esters and sulfonyl chlorides for the preparation of sulfonamides. | Wilden, JD., et al. 2007. Chem Commun (Camb). 1074-6. PMID: 17325810
- Concurrent anion..pi interactions between a perchlorate ion and two pi-acidic aromatic rings, namely pentafluorophenol and 1,3,5-triazine. | Götz, RJ., et al. 2008. Chem Commun (Camb). 3384-6. PMID: 18633497
- Effects of the [OC6F5] moiety upon structural geometry: crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(N(t)Bu)(CH2R)2 with pentafluorophenol. | Cole, JM., et al. 2011. Acta Crystallogr B. 67: 416-24. PMID: 21931211
- Desymmetrization of myo-inositol derivatives by lanthanide catalyzed phosphitylation with C2-symmetric phosphites. | Duss, M., et al. 2015. Bioorg Med Chem. 23: 2854-61. PMID: 25817239
- Electronic spectra and excited state dynamics of pentafluorophenol: Effects of low-lying πσ(∗) states. | Karmakar, S., et al. 2015. J Chem Phys. 142: 184303. PMID: 25978887
- Photophysics of phenol and pentafluorophenol: The role of nonadiabaticity in the optical transition to the lowest bright 1ππ* state. | Rajak, K., et al. 2018. J Chem Phys. 148: 054301. PMID: 29421886
- Copper-Catalyzed Synthesis of Activated Sulfonate Esters from Boronic Acids, DABSO, and Pentafluorophenol. | Vedovato, V., et al. 2018. Org Lett. 20: 5493-5496. PMID: 30152703
- Synthesis and Functionalization of Periodic Copolymers. | Kubatzki, F., et al. 2017. Polymers (Basel). 9: PMID: 30970845
- Enzyme-Catalyzed Kinetic Resolution of Chiral Precursors to Antiviral Prodrugs. | Xiang, DF., et al. 2019. Biochemistry. 58: 3204-3211. PMID: 31268686
- Atmospheric Chemistry of Pentafluorophenol: Kinetics and Mechanism of the Reactions of Cl Atoms and OH Radicals. | Hasager, F., et al. 2019. J Phys Chem A. 123: 10315-10322. PMID: 31665882
- Effects of Ring Fluorination on the Ultraviolet Photodissociation Dynamics of Phenol. | Cooper, GA., et al. 2020. J Phys Chem A. 124: 9698-9709. PMID: 33179506
- One-Pot Synthesis of Pentafluorophenyl Sulfonic Esters via Copper-Catalyzed Reaction of Aryl Diazonium Salts, DABSO, and Pentafluorophenol. | Idris, MA. and Lee, S. 2021. Org Lett. 23: 4516-4520. PMID: 33978431
- Diastereodivergent Aldol-Type Coupling of Alkoxyallenes with Pentafluorophenyl Esters Enabled by Synergistic Palladium/Chiral Lewis Base Catalysis. | Zhu, M., et al. 2022. Angew Chem Int Ed Engl. 61: e202207621. PMID: 35713176
- Pentafluorophenol (C6 F5 OH) Catalyzed Pictet-Spengler Reaction: A Facile and Metal-Free Approach Towards Tetrahydro-β-Carbolines. | Mahato, R. and Hazra, CK. 2023. Chemistry. 29: e202203924. PMID: 36922904
- Cytochrome P450-mediated oxidation of pentafluorophenol to tetrafluorobenzoquinone as the primary reaction product. | den Besten, C., et al. 1993. Chem Res Toxicol. 6: 674-80. PMID: 8292746
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Pentafluorophenol, 5 g | sc-253247 | 5 g | $23.00 | |||
Pentafluorophenol, 10 g | sc-253247A | 10 g | $65.00 |