Molecular structure of Palladium hydroxide on carbon, CAS Number: 12135-22-7
Palladium hydroxide on carbon (CAS 12135-22-7)
Alternate Names:
Pearlman′s catalyst
Application:
Palladium hydroxide on carbon is a catalyst for arylation reactions
CAS Number:
12135-22-7
Molecular Weight:
140.43
Molecular Formula:
H2O2Pd
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
Palladium hydroxide on carbon catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes. The addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation. Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proved successful where other palladium-on-carbon catalysts have failed.
Palladium hydroxide on carbon (CAS 12135-22-7) References
- Facile and efficient total synthesis of (+)-preussin. | Lee, KY., et al. 2000. Org Lett. 2: 4041-2. PMID: 11112638
- De novo synthesis of a methylene-bridged Neu5Ac-alpha-(2,3)-gal C-disaccharide. | Notz, W., et al. 2001. J Org Chem. 66: 4250-60. PMID: 11397161
- Efficient Synthesis of Ephedra Alkaloid Analogues Using an Enantiomerically Pure N-[(R)-(+)-alpha-Methylbenzyl]aziridine-2-carboxaldehyde. | Hwang, GI., et al. 1996. J Org Chem. 61: 6183-6188. PMID: 11667453
- Pd(OH)2/C (Pearlman's catalyst): a highly active catalyst for Fukuyama, Sonogashira, and Suzuki coupling reactions. | Mori, Y. and Seki, M. 2003. J Org Chem. 68: 1571-4. PMID: 12585906
- Golgi endomannosidase inhibitor, alpha-D-glucopyranosyl-(1 --> 3)-1-deoxymannojirimycin: a five-step synthesis from maltulose and examples of N-modified derivatives. | Spreitz, J. and Stütz, AE. 2004. Carbohydr Res. 339: 1823-7. PMID: 15220094
- Direct arylation reactions catalyzed by Pd(OH)2/C: evidence for a soluble palladium catalyst. | Parisien, M., et al. 2005. J Org Chem. 70: 7578-84. PMID: 16149786
- Simultaneous removal of benzyl and benzyloxycarbonyl protective groups in 5'-O-(2-deoxy-alpha-D-glucopyranosyl)uridine by catalytic transfer hydrogenolysis. | Wandzik, I., et al. 2008. Nucleosides Nucleotides Nucleic Acids. 27: 1250-6. PMID: 19003570
- S(N)1-type substitution reactions of N-protected β-hydroxytyrosine esters: stereoselective synthesis of β-aryl and β-alkyltyrosines. | Wilcke, D., et al. 2012. Chem Asian J. 7: 1372-82. PMID: 22407877
- The fine structure of Pearlman's catalyst. | Albers, PW., et al. 2015. Phys Chem Chem Phys. 17: 5274-8. PMID: 25607379
- 4-Alkylated Silver-N-Heterocyclic Carbene (NHC) Complexes with Cytotoxic Effects in Leukemia Cells. | Sandtorv, AH., et al. 2015. ChemMedChem. 10: 1522-7. PMID: 26250720
- The first total synthesis of gobichelin B: a mixed-ligand siderophore of Streptomyces sp. NRRL F-4415. | Sridhar, PR., et al. 2018. Org Biomol Chem. 16: 3732-3740. PMID: 29565443
- Facile Access to Optically Active 2,6-Dialkyl-1,5-Diazacyclooctanes. | Chulakova, DR., et al. 2019. Chem Asian J. 14: 4048-4054. PMID: 31381243
- Palladium Hydroxide (Pearlman's Catalyst) Doped MXene (Ti3C2Tx) Composite Modified Electrode for Selective Detection of Nicotine in Human Sweat. | Magesh, V., et al. 2022. Biosensors (Basel). 13: PMID: 36671889
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Palladium hydroxide on carbon, 1 g | sc-250642 | 1 g | $62.00 | |||
Palladium hydroxide on carbon, 10 g | sc-250642A | 10 g | $327.00 | |||
Palladium hydroxide on carbon, 500 g | sc-250642B | 500 g | $12839.00 | |||
Palladium hydroxide on carbon, 1 kg | sc-250642C | 1 kg | $20808.00 |