Molecular structure of Magnesium iodide, CAS Number: 10377-58-9
Magnesium iodide (CAS 10377-58-9)
Alternate Names:
diiodomagnesium; MgI2
Application:
Magnesium iodide is a useful reagent in Baylis-Hillman reactions
CAS Number:
10377-58-9
Molecular Weight:
278.11
Molecular Formula:
MgI2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
Magnesium iodide is an air-sensitive ionic solid that reacts with cyclic sulfates of vic-diols to produce corresponding olefins in excellent yields. Magnesium iodide can also be used to prepare compounds for organic synthesis, and may act to be very useful in the Baylis-Hillman reaction. Magnesium iodide finds application in diverse chemical reactions, including organic compound synthesis, polymer synthesis, and catalyst preparation.
Magnesium iodide (CAS 10377-58-9) References
- Magnesium iodide promoted reactions of nitrones with cyclopropanes: a synthesis of tetrahydro-1,2-oxazines. | Ganton, MD. and Kerr, MA. 2004. J Org Chem. 69: 8554-7. PMID: 15549844
- C-2 Epimerization of aldonolactones promoted by magnesium iodide: a new way towards non-enzymatic epimerization. | Gratien, J., et al. 2008. Carbohydr Res. 343: 18-30. PMID: 18005947
- Selective demethylation and debenzylation of aryl ethers by magnesium iodide under solvent-free conditions and its application to the total synthesis of natural products. | Bao, K., et al. 2009. Org Biomol Chem. 7: 5084-90. PMID: 20024102
- Total synthesis and cytotoxic activity of stellatin. | Saeed, A., et al. 2011. J Asian Nat Prod Res. 13: 97-104. PMID: 21279872
- Magnesium-Doped MAPbI3 Perovskite Layers for Enhanced Photovoltaic Performance in Humid Air Atmosphere. | Yang, F., et al. 2018. ACS Appl Mater Interfaces. 10: 24543-24548. PMID: 29969012
- Hydromagnesiation of 1,3-Enynes by Magnesium Hydride for Synthesis of Tri- and Tetra-substituted Allenes. | Wang, B., et al. 2021. Angew Chem Int Ed Engl. 60: 217-221. PMID: 32936502
- Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides. | Wang, B., et al. 2020. Chem Sci. 11: 5267-5272. PMID: 34122983
- Synthesis of α-Alkynylnitrones via Hydromagnesiation of 1,3-Enynes with Magnesium Hydride. | Li, Y., et al. 2021. Org Lett. 23: 5060-5064. PMID: 34125560
- Effect of Interface Modification on Mechanoluminescence-Inorganic Perovskite Impact Sensors. | Braga Carani, L., et al. 2022. Sensors (Basel). 23: PMID: 36616833
- Generation of Allylmagnesium Reagents by Hydromagnesiation of 2-Aryl-1,3-dienes. | Li, Y., et al. 2023. Angew Chem Int Ed Engl. 62: e202217735. PMID: 36637448
- Non-hydrolytic cleavage of esters with magnesium iodide in aprotic non-polar solvents. | Martínez, A. G., Barcinaa, J. O., del Veccio, G. H., Hanack, M., & Subramanian, L. R. 1991. Tetrahedron letters. 32(42): 5931-5934.
- Magnesium iodide promoted defluorinative reactions of 2, 2-difluorocyclopropyl aryl ketones with aryl imines: A new, general synthesis of 2-alkylideneazetidines | Xu, W., Ghiviriga, I., Chen, Q. Y., & Dolbier, W. R. 2010. Journal of Fluorine Chemistry. 131(9): 958-963.
- Aerobic photooxidative synthesis of benzimidazoles from aromatic aldehydes and diamines using catalytic amounts of magnesium iodide | Nagasawa, Y., Matsusaki, Y., Hotta, T., Nobuta, T., Tada, N., Miura, T., & Itoh, A. 2014. Tetrahedron Letters. 55(48): 6543-6546.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Magnesium iodide, 5 g | sc-252983 | 5 g | $88.00 | |||
Magnesium iodide, 25 g | sc-252983A | 25 g | $286.00 |