Date published: 2026-2-4

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Lithium tetrafluoroborate (CAS 14283-07-9)

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Alternate Names:
Lithium fluoroborate; Lithium borofluoride
CAS Number:
14283-07-9
Molecular Weight:
93.75
Molecular Formula:
BF4Li
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Lithium tetrafluoroborate (LiBF4) is a lithium and boron salt widely employed in various applications, both in industrial settings and scientific research. This white, odorless, and tasteless solid exhibits solubility in water and alcohol. It serves as a reagent in organic synthesis and functions as a catalyst in biochemical reactions. In scientific research, Lithium tetrafluoroborate has been extensively utilized across multiple disciplines. Its applications span chemical synthesis, electrochemistry, and biochemistry. The role of Lithium tetrafluoroborate in biochemical reactions involves catalyzing electron transfer between molecules. Furthermore, it acts as an electrolyte, enabling the movement of ions between solutions.


Lithium tetrafluoroborate (CAS 14283-07-9) References

  1. LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds.  |  Yadav, JS., et al. 2001. Carbohydr Res. 332: 221-4. PMID: 11434381
  2. Ion-dipole interactions in concentrated organic electrolytes.  |  Chagnes, A., et al. 2003. Chemphyschem. 4: 559-66. PMID: 12836478
  3. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts.  |  Kuchenbeiser, G., et al. 2009. Chem Asian J. 4: 1745-50. PMID: 19780080
  4. Superhydrophobic conducting polymers based on hydrocarbon poly(3,4-ethylenedioxyselenophene).  |  Dunand, O., et al. 2013. Chemphyschem. 14: 2947-53. PMID: 23893504
  5. FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate+diethyl carbonate mixtures.  |  Zhang, B., et al. 2014. Spectrochim Acta A Mol Biomol Spectrosc. 122: 59-64. PMID: 24295777
  6. Introducing manganese complexes as redox mediators for dye-sensitized solar cells.  |  Perera, IR., et al. 2014. Phys Chem Chem Phys. 16: 12021-8. PMID: 24394772
  7. Li(+)-molecule interactions of lithium tetrafluoroborate in propylene carbonate + N,N-dimethylformamide mixtures: an FTIR spectroscopic study.  |  Zhang, B., et al. 2014. Spectrochim Acta A Mol Biomol Spectrosc. 124: 40-5. PMID: 24463238
  8. Molecular dynamics simulations of the structure of the graphene-ionic liquid/alkali salt mixtures interface.  |  Méndez-Morales, T., et al. 2014. Phys Chem Chem Phys. 16: 13271-8. PMID: 24871696
  9. Photolysis of Tertiary Amines in the Presence of CO2: The Paths to Formic Acid, α-Amino Acids, and 1,2-Diamines.  |  Berton, M., et al. 2018. J Org Chem. 83: 96-103. PMID: 29239181
  10. Bis-aminocyclopropenylidene carbene borane catalyzed imine hydrogenation.  |  Huchenski, BSN., et al. 2019. Org Biomol Chem. 17: 6158-6164. PMID: 31183491
  11. Strong cellulose hydrogel as underwater superoleophobic coating for efficient oil/water separation.  |  Xie, X., et al. 2020. Carbohydr Polym. 229: 115467. PMID: 31826446
  12. Anion Intercalation into a Graphite Electrode from Trimethyl Phosphate.  |  Zhang, L. and Wang, H. 2020. ACS Appl Mater Interfaces. 12: 47647-47654. PMID: 33030890
  13. Interplay of Structure and Dynamics in Lithium/Ionic Liquid Electrolytes: Experiment and Molecular Simulation.  |  Judeinstein, P., et al. 2021. J Phys Chem B. 125: 1618-1631. PMID: 33535754
  14. Difluoro(oxalato)borate's Role in the Intercalation Behavior of Mixed Anions from Sulfolane.  |  Wang, Y., et al. 2023. ChemSusChem. 16: e202201218. PMID: 36039804

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Lithium tetrafluoroborate, 5 g

sc-286139
5 g
$36.00

Lithium tetrafluoroborate, 25 g

sc-286139A
25 g
$74.00

Lithium tetrafluoroborate, 100 g

sc-286139B
100 g
$172.00

Lithium tetrafluoroborate, 500 g

sc-286139C
500 g
$520.00

Lithium tetrafluoroborate, 1 kg

sc-286139D
1 kg
$2289.00