Date published: 2025-10-7

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Lithium difluoro(oxalato)borate (CAS 409071-16-5)

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Alternate Names:
Lithium oxalatodigluoroborate; LIF2OB
Application:
Lithium difluoro(oxalato)borate is a metal salt for research in high-performance batteries
CAS Number:
409071-16-5
Molecular Weight:
143.77
Molecular Formula:
C2BF2LiO4
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Lithium difluoro(oxalato)borate (LIODFB) is a salt for researching high-performance Li-ion batteries with improved cycle life power capability low temperature and high rate performance of the battery. It has the advantages of both lithium bis(oxalato)borate (LiBOB) and LiBF4. Lithium difluoro(oxalato)borate also stabilizes the solid electrolyte interface (SEI) on the surface of a graphite anode and is also used as an additive to improve the cycling efficiency and capacity retention of cells.


Lithium difluoro(oxalato)borate (CAS 409071-16-5) References

  1. Studies on electrochemical performances of novel electrolytes for wide-temperature-range lithium-ion batteries.  |  Li, S., et al. 2014. ACS Appl Mater Interfaces. 6: 4920-6. PMID: 24611743
  2. An enhanced electrochemical and cycling properties of novel boronic Ionic liquid based ternary gel polymer electrolytes for rechargeable Li/LiCoO2 cells.  |  Karuppasamy, K., et al. 2017. Sci Rep. 7: 11103. PMID: 28894241
  3. Mechanistic Study of Electrolyte Additives to Stabilize High-Voltage Cathode-Electrolyte Interface in Lithium-Ion Batteries.  |  Gao, H., et al. 2017. ACS Appl Mater Interfaces. 9: 44542-44549. PMID: 29211441
  4. Fluorinated Electrolytes for Li-Ion Batteries: The Lithium Difluoro(oxalato)borate Additive for Stabilizing the Solid Electrolyte Interphase.  |  Xia, L., et al. 2017. ACS Omega. 2: 8741-8750. PMID: 31457404
  5. Functional Electrolyte of Fluorinated Ether and Ester for Stabilizing Both 4.5 V LiCoO2 Cathode and Lithium Metal Anode.  |  Lin, S. and Zhao, J. 2020. ACS Appl Mater Interfaces. 12: 8316-8323. PMID: 31944648
  6. Enabling a Durable Electrochemical Interface via an Artificial Amorphous Cathode Electrolyte Interphase for Hybrid Solid/Liquid Lithium-Metal Batteries.  |  Liang, JY., et al. 2020. Angew Chem Int Ed Engl. 59: 6585-6589. PMID: 32017343
  7. The Roles and Working Mechanism of Salt-Type Additives on the Performance of High-Voltage Lithium-Ion Batteries.  |  Li, Y., et al. 2020. ACS Appl Mater Interfaces. 12: 16298-16307. PMID: 32216273
  8. LiDFOB Initiated In Situ Polymerization of Novel Eutectic Solution Enables Room-Temperature Solid Lithium Metal Batteries.  |  Wu, H., et al. 2020. Adv Sci (Weinh). 7: 2003370. PMID: 33304769
  9. High-Efficacy and Polymeric Solid-Electrolyte Interphase for Closely Packed Li Electrodeposition.  |  Li, S., et al. 2021. Adv Sci (Weinh). 8: 2003240. PMID: 33747731
  10. Novel Low-Temperature Electrolyte Using Isoxazole as the Main Solvent for Lithium-Ion Batteries.  |  Tan, S., et al. 2021. ACS Appl Mater Interfaces. 13: 24995-25001. PMID: 34010556
  11. Electrolyte Additives for Improving the High-Temperature Storage Performance of Li-Ion Battery NCM523∥Graphite with Overcharge Protection.  |  Gu, Q., et al. 2022. ACS Appl Mater Interfaces. 14: 4759-4766. PMID: 35015503
  12. Quantifying the Evolution of Inactive Li/Lithium Hydride and Their Correlations in Rechargeable Anode-free Li Batteries.  |  Tao, M., et al. 2022. Nano Lett. 22: 6775-6781. PMID: 35939759
  13. Difluoro(oxalato)borate's Role in the Intercalation Behavior of Mixed Anions from Sulfolane.  |  Wang, Y., et al. 2023. ChemSusChem. 16: e202201218. PMID: 36039804
  14. Tailoring electrolyte enables high-voltage Ni-rich NCM cathode against aggressive cathode chemistries for Li-ion batteries.  |  Cheng, F., et al. 2022. Sci Bull (Beijing). 67: 2225-2234. PMID: 36545998
  15. Improved Cycling of Li||NMC811 Batteries under Practical Conditions by a Localized High-Concentration Electrolyte.  |  Guo, F., et al. 2023. Small. e2207290. PMID: 36670341

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Lithium difluoro(oxalato)borate, 25 g

sc-396975
25 g
$223.00