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Lanthanum(III) chloride bis(lithium chloride) complex solution (CAS 405204-22-0)

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Application:
Lanthanum(III) chloride bis(lithium chloride) complex solution is A biochemical that mediates Grignard additions
CAS Number:
405204-22-0
Molecular Weight:
330.05
Molecular Formula:
LaCl32LiCl
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Available in US only.
* Refer to Certificate of Analysis for lot specific data.

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Lanthanum(III) chloride bis(lithium chloride) complex solution is a biochemical that mediates Grignard additions. It is also a reagent for metal exchange reactions and a promoter for the addition of organometallic compounds to sterically hindered (enolizable or alpha,beta-unsaturated) ketones or imines. Lanthanum(III) chloride bis(lithium chloride) complex solution has various scientific research applications, including as a solid-state electrolyte for lithium-ion batteries, a scintillator material for gamma-ray detection, and a neutron detector material. It is also used as a host material for rare-earth ions, which can be used in optical applications such as lasers and phosphors. Additionally, the material has high ionic conductivity, which makes it useful for radiation detection applications.


Lanthanum(III) chloride bis(lithium chloride) complex solution (CAS 405204-22-0) References

  1. Asymmetric total synthesis of smyrindiol employing an organocatalytic aldol key step.  |  Enders, D., et al. 2012. Beilstein J Org Chem. 8: 1112-7. PMID: 23019438
  2. A Bioinspired Cyclization Sequence Enables the Asymmetric Total Synthesis of Dictyoxetane.  |  Hugelshofer, CL. and Magauer, T. 2016. J Am Chem Soc. 138: 6420-3. PMID: 27159010
  3. A Divergent Approach to the Marine Diterpenoids (+)-Dictyoxetane and (+)-Dolabellane V.  |  Hugelshofer, CL. and Magauer, T. 2016. Chemistry. 22: 15125-15136. PMID: 27601319
  4. Ring-Expansion Approaches for the Total Synthesis of Salimabromide.  |  Schmid, M., et al. 2019. Tetrahedron. 75: 3195-3215. PMID: 31160829
  5. Calyciphylline B-type Alkaloids: Evolution of a Synthetic Strategy to (-)-Daphlongamine H.  |  Hugelshofer, CL., et al. 2019. J Org Chem. 84: 14069-14091. PMID: 31533427
  6. The chemistry and biology of guanidine secondary metabolites.  |  Berlinck, RGS., et al. 2021. Nat Prod Rep. 38: 586-667. PMID: 33021301
  7. Tetrahydrofuran-Based Transient Receptor Potential Ankyrin 1 (TRPA1) Antagonists: Ligand-Based Discovery, Activity in a Rodent Asthma Model, and Mechanism-of-Action via Cryogenic Electron Microscopy.  |  Terrett, JA., et al. 2021. J Med Chem. 64: 3843-3869. PMID: 33749283
  8. A convergent approach to batzelladine alkaloids. Total syntheses of (+)-batzelladine E, (-)-dehydrobatzelladine C, and (+)-batzelladine K.  |  Economou, C., et al. 2018. Tetrahedron. 74: 3188-3197. PMID: 33911315
  9. Development of an Enantioselective Synthesis of (-)-Euonyminol.  |  Tomanik, M., et al. 2021. J Org Chem. 86: 17011-17035. PMID: 34784213
  10. Total Syntheses of (±)-Dracocephalone A and (±)-Dracocequinones A and B.  |  Hwang, T., et al. 2022. Angew Chem Int Ed Engl. 61: e202210821. PMID: 36121442

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Lanthanum(III) chloride bis(lithium chloride) complex solution, 100 ml

sc-300902
100 ml
$151.00
US: Only available in the US

Lanthanum(III) chloride bis(lithium chloride) complex solution, 1 L

sc-300902A
1 L
$1390.00
US: Only available in the US

Lanthanum(III) chloride bis(lithium chloride) complex solution, 5 L

sc-300902B
5 L
$6944.00
US: Only available in the US

Lanthanum(III) chloride bis(lithium chloride) complex solution, 10 L

sc-300902C
10 L
$14056.00
US: Only available in the US

When can it be delivered after ordering?

Asked by: Robert1
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Answered by: Technical Support
Date published: 2018-02-14
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Rated 5 out of 5 by from The Lanthanum(III) chloride bis(LiCl) complexThe Lanthanum(III) chloride bis(LiCl) complex is used to facilitate metal exchange reactions. In addition, it can be used to promote organometallic additions (i.e. Grignards) to challenging substrate-electrophiles such as sterically-congested and/or enolizable ketones.
Date published: 2015-10-13
Rated 5 out of 5 by from Lanthanum(III) chloride bis(lithium chloride)Lanthanum(III) chloride bis(lithium chloride) complex solution was utilized as a reagent for metal exchange reactions, in many articles. -SCBT Publication Review
Date published: 2015-01-27
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Lanthanum(III) chloride bis(lithium chloride) complex solution is rated 5.0 out of 5 by 2.
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