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Isopropenyl acetate (CAS 108-22-5)

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Alternate Names:
1-Methylvinyl acetate
Application:
Isopropenyl acetate is a biochemical used for proteomics research
CAS Number:
108-22-5
Molecular Weight:
100.12
Molecular Formula:
C5H8O2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Isopropenyl acetate is a biochemical used for proteomics research. Isopropenyl acetate forms copolyperoxides of different compositions with indene by the free radical-initiated oxidative copolymerization. In industrial applications, isopropenyl acetate is often used as a solvent and intermediate in the synthesis of other chemical compounds. Its effectiveness as a solvent stems from its ability to dissolve a wide range of organic materials. This property is particularly useful in formulations where a fast-evaporating solvent is required.


Isopropenyl acetate (CAS 108-22-5) References

  1. Metal-catalyzed acyl transfer reactions of enol esters: role of Y5(OiPr)13O and (thd)2Y(OiPr) as transesterification catalysts.  |  Lin, MH. and RajanBabu, TV. 2000. Org Lett. 2: 997-1000. PMID: 10768206
  2. Lipase-catalyzed irreversible transesterification of 1-(2-furyl)ethanol using isopropenyl acetate.  |  Ghanem, A. and Schurig, V. 2001. Chirality. 13: 118-23. PMID: 11170255
  3. An Efficient Acylation of Tertiary Alcohols with Isopropenyl Acetate Mediated by an Oxime Ester and Cp(2)Sm(thf)(2).  |  Tashiro, D., et al. 1997. J Org Chem. 62: 8141-8144. PMID: 11671923
  4. Efficient lipase-catalyzed enantioselective desymmetrization of prochiral 2,2-disubstituted 1,3-propanediols and meso 1,2-diols using 1-ethoxyvinyl 2-furoate.  |  Akai, S., et al. 2002. J Org Chem. 67: 411-9. PMID: 11798311
  5. Enol esters: versatile substrates for Mannich-type multicomponent reactions.  |  Isambert, N., et al. 2007. Org Lett. 9: 4199-202. PMID: 17867693
  6. Direct synthesis of anti-1,3-diols through nonclassical reaction of aryl Grignard reagents with isopropenyl acetate.  |  Jiao, Y., et al. 2011. Org Lett. 13: 180-3. PMID: 21142039
  7. Per-O-acetylation of cellulose in dimethyl sulfoxide with catalyzed transesterification.  |  Chen, CY., et al. 2014. J Agric Food Chem. 62: 3446-52. PMID: 24678805
  8. UV resistance and dimensional stability of wood modified with isopropenyl acetate.  |  Nagarajappa, GB. and Pandey, KK. 2016. J Photochem Photobiol B. 155: 20-7. PMID: 26722999
  9. Lipase-catalyzed kinetic resolution as key step in the synthesis of enantiomerically pure σ ligands with 2-benzopyran structure.  |  Knappmann, I., et al. 2017. Bioorg Med Chem. 25: 3384-3395. PMID: 28501431
  10. Biocatalytic Friedel-Crafts Acylation and Fries Reaction.  |  Schmidt, NG., et al. 2017. Angew Chem Int Ed Engl. 56: 7615-7619. PMID: 28544673
  11. A New Family of Renewable Thermosets: Kraft Lignin Poly-adipates.  |  Di Francesco, D., et al. 2022. ChemSusChem. 15: e202200326. PMID: 35312238
  12. A Stoichiometric Solvent-Free Protocol for Acetylation Reactions.  |  Valentini, F., et al. 2022. Front Chem. 10: 842190. PMID: 35355791
  13. Cellulose triacetate synthesis via one-pot organocatalytic transesterification and delignification of pretreated bagasse.  |  Suzuki, S., et al. 2018. RSC Adv. 8: 21768-21776. PMID: 35541740
  14. Dimethyl Sulfoxide-Assisted, Iodine- and Ascorbic Acid-Catalyzed One-Pot Synthetic Approach for Constructing Highly Substituted Pyrazolo[1,5-a]quinoline Thioether Derivatives.  |  Saritha, R., et al. 2022. J Org Chem. 87: 13856-13872. PMID: 36215433

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Isopropenyl acetate, 250 ml

sc-396799
250 ml
$41.00

Isopropenyl acetate, 1 L

sc-396799A
1 L
$108.00