Date published: 2026-3-19

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Iodine monochloride (CAS 7790-99-0)

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Application:
Iodine monochloride is a useful synthetic reagent and source of I+
CAS Number:
7790-99-0
Molecular Weight:
162.36
Molecular Formula:
ICl
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Available in US only.
* Refer to Certificate of Analysis for lot specific data.

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Iodine monochloride, a yellowish-red, volatile compound, is widely utilized in scientific research, particularly in organic synthesis and halogenation reactions. Its mechanism of action primarily involves its role as a selective halogenating agent, where it facilitates the introduction of chlorine atoms into organic molecules. In organic chemistry, iodine monochloride serves as a valuable reagent for the conversion of alcohols to chlorides, particularly in the synthesis of pharmaceutical intermediates and agrochemicals. Additionally, it finds application in the preparation of various functional groups, including chloroalkanes, chloroethers, and chloroketones, through halogenation reactions. Furthermore, iodine monochloride plays a crucial role in oxidative transformations, such as the conversion of primary alcohols to aldehydes and secondary alcohols to ketones, providing chemists with efficient synthetic routes for the production of diverse organic compounds. Beyond its use in organic synthesis, iodine monochloride also finds applications in materials science, where it is employed as a dopant in the fabrication of conducting polymers and as a precursor for the synthesis of iodine-containing compounds with potential applications in photovoltaics and optoelectronics. Overall, iodine monochloride serves as a versatile reagent in scientific research, enabling the synthesis of complex organic molecules and functional materials through its selective halogenation and oxidative capabilities.


Iodine monochloride (CAS 7790-99-0) References

  1. Iodine monochloride and iodine trichloride as chlorinating agents.  |  GANDBHIR, AM., et al. 1950. Curr Sci. 19: 380. PMID: 14802068
  2. A novel spectrophotometric determination of some phenothiazines involving iodine monochloride from chloramine-T with iodine.  |  Gowtham, MD., et al. 2004. Arch Pharm (Weinheim). 337: 605-14. PMID: 15543534
  3. The role of iodine monochloride for the oxidation of elemental mercury.  |  Qu, Z., et al. 2010. J Hazard Mater. 183: 132-7. PMID: 20674159
  4. Ultraviolet photodissociation of iodine monochloride (ICl) at 235, 250, and 265 nm.  |  Diamantopoulou, N., et al. 2011. J Chem Phys. 134: 194314. PMID: 21599066
  5. Iodine monochloride facilitated deglycosylation, anomerization, and isomerization of 3-substituted thymidine analogues.  |  Khalil, A., et al. 2014. Nucleosides Nucleotides Nucleic Acids. 33: 786-99. PMID: 25372994
  6. Electrochemistry of Iodide, Iodine, and Iodine Monochloride in Chloride Containing Nonhaloaluminate Ionic Liquids.  |  Bentley, CL., et al. 2016. Anal Chem. 88: 1915-21. PMID: 26708364
  7. A new study of iodine complexes of oxidized gum arabic: An interaction between iodine monochloride and aldehyde groups.  |  Ali, A., et al. 2018. Carbohydr Polym. 180: 337-347. PMID: 29103513
  8. Absolute Band Intensity of the Iodine Monochloride Fundamental Mode for Infrared Sensing and Quantitative Analysis.  |  Hughey, KD., et al. 2020. J Phys Chem A. 124: 9578-9588. PMID: 33153259
  9. Role of Iodine Recycling on Sea-Salt Aerosols in the Global Marine Boundary Layer.  |  Li, Q., et al. 2022. Geophys Res Lett. 49: e2021GL097567. PMID: 35859565
  10. Cluster halogenation of adamantane and its derivatives with bromine and iodine monochloride.  |  Shernyukov, AV., et al. 2022. Org Biomol Chem. 20: 8515-8527. PMID: 36278729

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Iodine monochloride, 25 g

sc-211649
25 g
$66.00
US: Only available in the US

Iodine monochloride, 100 g

sc-211649A
100 g
$154.00
US: Only available in the US