Molecular structure of Hydroxy(cyclooctadiene)rhodium(I) dimer, CAS Number: 73468-85-6
Hydroxy(cyclooctadiene)rhodium(I) dimer (CAS 73468-85-6)
Alternate Names:
(Cyclooctadiene)rhodium hydroxide dimer
Application:
Hydroxy(cyclooctadiene)rhodium(I) dimer is a rhodium catalyst
CAS Number:
73468-85-6
Molecular Weight:
456.19
Molecular Formula:
C16H26O2Rh2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
Rhodium catalyst is used with R-BINAP or R-SEGPHOS ligands in a synthesis of chiral 3,3-disubstituted-1-indanones.(1)
Hydroxy(cyclooctadiene)rhodium(I) dimer (CAS 73468-85-6) References
- Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones. | Shintani, R., et al. 2007. Angew Chem Int Ed Engl. 46: 3735-7. PMID: 17407122
- Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: the enantioselective synthesis of hermitamides A and B. | Frost, CG., et al. 2008. Org Biomol Chem. 6: 4340-7. PMID: 19005593
- Total synthesis of (-)-tubingensin B enabled by the strategic use of an aryne cyclization. | Corsello, MA., et al. 2017. Nat Chem. 9: 944-949. PMID: 28937679
- C-H/C-C Functionalization Approach to N-Fused Heterocycles from Saturated Azacycles. | Ham, JS., et al. 2020. J Am Chem Soc. 142: 13041-13050. PMID: 32627545
- Invention of MK-8262, a Cholesteryl Ester Transfer Protein (CETP) Inhibitor Backup to Anacetrapib with Best-in-Class Properties. | Vachal, P., et al. 2021. J Med Chem. 64: 13215-13258. PMID: 34375108
- Rhodium-Catalyzed Atroposelective Click Cycloaddition of Azides and Alkynes. | Zeng, L., et al. 2022. Angew Chem Int Ed Engl. 61: e202205037. PMID: 35508703
- B(C6F5)3-Catalyzed Group Transfer Polymerization of n-Butyl Acrylate with Hydrosilane through In Situ Formation of Initiator by 1,4-Hydrosilylation of n-Butyl Acrylate. | Fuchise, K., et al. 2014. ACS Macro Lett. 3: 1015-1019. PMID: 35610785
- Rhodium(I)-Catalyzed Defluorinative Coupling of Boronic Acids with Monofluoroalkenes. | Zong, Y., et al. 2022. Org Lett. 24: 6380-6385. PMID: 35925659
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Hydroxy(cyclooctadiene)rhodium(I) dimer, 250 mg | sc-252896 | 250 mg | $272.00 |