Date published: 2026-4-28

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Hexafluoroisopropyl crotonate (CAS 135771-94-7)

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CAS Number:
135771-94-7
Molecular Weight:
236.11
Molecular Formula:
C7H6F6O2
Supplemental Information:
This is as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Hexafluoroisopropyl crotonate is a fluorinated ester that is of significant interest in organic synthesis and materials chemistry research. Its heavily fluorinated isopropyl group imparts unique physical and chemical properties, such as high thermal stability and chemical resistance, which are beneficial in creating polymers and coatings with enhanced performance characteristics. The crotonate moiety, a conjugated system, allows for reactions typical of α,β-unsaturated carbonyl compounds, such as Michael additions or Diels-Alder reactions, making it a valuable monomer in the preparation of advanced polymeric materials. Researchers explore the utility of Hexafluoroisopropyl crotonate in initiating polymerization processes due to its reactive double bond. Additionally, the electron-withdrawing nature of the fluorinated groups can shift the electron density of the molecule, affecting its reactivity and making it a subject of study in the development of fluorine-containing organic compounds.


Hexafluoroisopropyl crotonate (CAS 135771-94-7) References

  1. Broad-spectrum enantioselective diels-alder catalysis by chiral, cationic oxazaborolidines.  |  Ryu, DH., et al. 2002. J Am Chem Soc. 124: 9992-3. PMID: 12188655

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Hexafluoroisopropyl crotonate, 5 g

sc-257585
5 g
$214.00