Molecular structure of Hexafluoroacetylacetone, CAS Number: 1522-22-1
Hexafluoroacetylacetone (CAS 1522-22-1)
Alternate Names:
1,1,1,5,5,5-Hexafluoro-2,4-pentanedione; 1,1,1,5,5,5-Hexafluoroacetylacetone
Application:
Hexafluoroacetylacetone is Hexafluoroacetylacetone is a chelating ligand.
CAS Number:
1522-22-1
Molecular Weight:
208.06
Molecular Formula:
C5H2F6O2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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SDS & Certificate of Analysis
Hexafluoroacetylacetone functions as a chelating agent in various experimental applications. It has the ability to form stable complexes with metal ions, which is for its role in analytical chemistry and metal extraction processes. Hexafluoroacetylacetone interacts with metal ions by coordinating with their electron-donating atoms, leading to the formation of stable coordination complexes. This chelating property allows hexafluoroacetylacetone to effectively sequester metal ions from solution, making it useful in the separation and purification of metal ions. At the molecular level, hexafluoroacetylacetone′s mechanism of action involves the formation of coordination bonds with metal ions, influencing their behavior and reactivity in various chemical processes.
Hexafluoroacetylacetone (CAS 1522-22-1) References
- Syntheses, structures, and properties of trinuclear complexes [M(bpca)(2)(M'(hfac)(2))(2)], constructed with the complexed bridging ligand [M(bpca)(2)] [M, M' = Ni(II), Mn(II); Cu(II), Mn(II); Fe(II), Mn(II); Ni(II), Fe(II); and Fe(II), Fe(II); Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone]. | Kamiyama, A., et al. 2002. Inorg Chem. 41: 507-12. PMID: 11825077
- Nature of copper(II)-lanthanide(III) magnetic interactions and generation of a large magnetic moment with magnetic anisotropy of 3d-4f cyclic cylindrical tetranuclear complexes [CuIILLnIII(hfac)2]2, (H3L = 1-(2-hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane and Hhfac = hexafluoroacetylacetone, LnIII = Eu, Gd, Tb, Dy). | Kido, T., et al. 2003. Inorg Chem. 42: 398-408. PMID: 12693220
- Substoichiometric extraction with hexafluoroacetylacetone and tri-n-octylphosphine oxide in cyclohexane Determination of manganese by neutron activation. | Mitchell, JW. and Ganges, R. 1974. Talanta. 21: 735-43. PMID: 18961525
- Optimization of the extraction of iron(II) from water into cyclohexane with hexafluoroacetylacetone and tri-n-butyl phosphate. | Turoff, ML. and Deming, SN. 1977. Talanta. 24: 567-71. PMID: 18962145
- Kinetics and mechanism for the reaction of hexafluoroacetylacetone with CuO in supercritical carbon dioxide. | Durando, M., et al. 2008. J Am Chem Soc. 130: 16659-68. PMID: 19049461
- Electronic structure and proton transfer in ground-state hexafluoroacetylacetone. | Chatterjee, C., et al. 2010. J Phys Chem A. 114: 6630-40. PMID: 20507165
- Photochemistry of UV-excited trifluoroacetylacetone and hexafluoroacetylacetone I: infrared spectra of fluorinated methylfuranones formed by HF photoelimination. | Muyskens, KJ., et al. 2012. J Phys Chem A. 116: 12305-13. PMID: 23176295
- Dissociative electron attachment to hexafluoroacetylacetone and its bidentate metal complexes M(hfac)2; M = Cu, Pd. | Engmann, S., et al. 2013. J Chem Phys. 138: 234309. PMID: 23802962
- Sensitization of visible and NIR emitting lanthanide(III) ions in noncentrosymmetric complexes of hexafluoroacetylacetone and unsubstituted monodentate pyrazole. | Ahmed, Z. and Iftikhar, K. 2013. J Phys Chem A. 117: 11183-201. PMID: 24160553
- Infrared and Near-Infrared Spectroscopy of Acetylacetone and Hexafluoroacetylacetone. | Howard, DL., et al. 2015. J Phys Chem A. 119: 7980-90. PMID: 25894207
- Surface Chemistry of Thermal Dry Etching of Cobalt Thin Films Using Hexafluoroacetylacetone (hfacH). | Zhao, J., et al. 2018. Appl Surf Sci. 455: 438-445. PMID: 29937610
- Hybrid Rare-Earth(III)/Bismuth(III) Clusters Assembled with Phosphonates. | Jin, JL., et al. 2019. Inorg Chem. 58: 648-654. PMID: 30525540
- GC Determination of Fluorouracil in Serum by Using Hexafluroroacetylacetone as Derivatizing Reagent. | Zounr, RA., et al. 2022. J Chromatogr Sci. 60: 409-413. PMID: 35024827
- Ultrafast X-ray Spectroscopy of Intersystem Crossing in Hexafluoroacetylacetone: Chromophore Photophysics and Spectral Changes in the Face of Electron-Withdrawing Groups. | Haugen, EA., et al. 2023. J Phys Chem A. 127: 634-644. PMID: 36638240
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| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Hexafluoroacetylacetone, 5 g | sc-257583 | 5 g | $40.00 |