Molecular structure of Ferrocenium tetrafluoroborate, CAS Number: 1282-37-7
Ferrocenium tetrafluoroborate (CAS 1282-37-7)
Alternate Names:
Bis(cyclopentadienyl)iron tetrafluoroborate; Dicyclopentadienyliron fluoborate; Dicyclopentadienyliron tetrafluoroborate
CAS Number:
1282-37-7
Molecular Weight:
272.84
Molecular Formula:
C10H10BF4Fe
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Ferrocenium tetrafluoroborate operates by initiating electron transfer from the cyclopenta-1,3-diene ligand to the iron(III) cation. This transfer leads to the creation of a stable cyclopenta-1,3-diene-iron(III) complex, which is further fortified by the tetrafluoroborate anion. This complex exhibits catalytic properties, enabling it to facilitate the intended reaction.
Ferrocenium tetrafluoroborate (CAS 1282-37-7) References
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- A functional nitric oxide reductase model. | Collman, JP., et al. 2008. Proc Natl Acad Sci U S A. 105: 15660-5. PMID: 18838684
- Ferrocenium salts mediate para-tert-butylcalixarene synthesis. | Bew, SP., et al. 2008. Chem Commun (Camb). 5731-3. PMID: 19009063
- Solvent and electrolyte effects on the kinetics of ferrocenium-ferrocene self-exchange. A reevaluation | Roger M. Nielson, George E. McManis, Lance K. Safford, and Michael J. Weaver. 1989,. J. Phys. Chem. 2152–2157: 93, 5,.
- Structure of a trinuclear dizirconium-aluminum (Zr2Al).mu.-ketone complex with a bridging trigonal-bipyramidal methyl group | Robert W. Waymouth, Kristine S. Potter, William P. Schaefer, and Robert H. Grubbs. 1990. Organometallics Publication Date:October 1, 1990., 9, 10,: 2843–2846.
- Syntheses and physicochemical properties of Cu(BF4)2 complexes of polythia[n]ferrocenophanes and the corresponding ferrocenium cations | Masaru Sato, Motomi Katada, Satoru Nakashima, Hirotoshi Sano and Sadatoshi Akabori. 1990,. J. Chem. Soc., Dalton Trans.,. Issue 6, 1990: 1979-1984.
- Substituent effects in multiply trimethylsilyl-substituted ferrocenes. Molecular structure of 1,1′,2,2′,4,4′-hexakis(trimethylsilyl)ferrocenium tetrafluoroborate | J Okuda, RW Albach, E Herdtweck, FE Wagner - Polyhedron, 1991 - Elsevier. 1991,. Polyhedron. Volume 10, Issue 15,: Pages 1741-1748.
- Irreversible Redox Reactions of Ferrocene/Ferrocenium on Self-Assembled Monolayer Modified Gold Electrode in Ionic Liquid BMIMBF4 | An D. Le1 and Lei Yu2,1. 2010. J. Electrochem. Soc. 158 F10. 158: F10.
- Applications of Ferrocenium Salts in Organic Synthesis | Štefan Toma*, et al. 2015. Synthesis.; 47(12):: 1683-1695.
- Difference in reactivity of triel halides EX3 towards ferrocene | S Scholz, M Scheibitz, F Schödel, M Bolte… - Inorganica chimica …, 2007 - Elsevier. 2 July 2007,. Inorganica Chimica Acta. Volume 360, Issue 10,: Pages 3323-3329.
- Selective oxidants for organometallic compounds containing a stabilising anion of highly reactive cations: (3,5(CF3)2C6H3)4B−)Cp2Fe+ and (3,5(CF3)2C6H3)4B−)Cp*2Fe+ | I Noviandri, KN Brown, DS Fleming… - The Journal of …, 1999 - ACS Publications. 20 April 2000,. Journal of Organometallic Chemistry. Volume 601, Issue 1,: Pages 126-132.
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| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Ferrocenium tetrafluoroborate, 5 g | sc-228122 | 5 g | $152.00 |