Date published: 2026-1-15

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ε-Caprolactam (CAS 105-60-2)

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Alternate Names:
2-Oxohexamethyleneimine; Aza-2-cycloheptanone; epsilon-Caprolactam
Application:
ε-Caprolactam is a synthetic precursor of Nylon-6 and other synthetic polymers.
CAS Number:
105-60-2
Purity:
≥99%
Molecular Weight:
113.16
Molecular Formula:
C6H11NO
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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ε-Caprolactam is a cyclic amide that serves as a precursor in the synthesis of polymers such as nylon-6. It undergoes a ring-opening polymerization reaction to form long chains of nylon-6, a material that finds application in the production of fibers, plastics, and other materials. In the presence of a catalyst, ε-Caprolactam reacts with itself to form a polymer chain, which can then be processed into various products. ε-Caprolactam′s mechanism of action involves the opening of its cyclic structure to form linear polymer chains, which can be further processed and utilized in various industrial applications. Its functional role lies in its ability to undergo polymerization reactions, leading to the formation of nylon-6 and other related polymers.


ε-Caprolactam (CAS 105-60-2) References

  1. Reusable task-specific ionic liquids for a clean ε-caprolactam synthesis under mild conditions.  |  Turgis, R., et al. 2010. ChemSusChem. 3: 1403-8. PMID: 21117118
  2. Isolation and characterization of a novel ε-caprolactam-degrading microbe, Acinetobacter calcoaceticus, from industrial wastewater by chemostat-enrichment.  |  Rajoo, S., et al. 2013. Biotechnol Lett. 35: 2069-72. PMID: 23974491
  3. Catalytic conversion of γ-valerolactone to ε-caprolactam: towards nylon from renewable feedstock.  |  Raoufmoghaddam, S., et al. 2014. ChemSusChem. 7: 1984-90. PMID: 24938779
  4. Development of a Transcription Factor-Based Lactam Biosensor.  |  Zhang, J., et al. 2017. ACS Synth Biol. 6: 439-445. PMID: 27997130
  5. A Review of Thermoplastic Resin Transfer Molding: Process Modeling and Simulation.  |  Ageyeva, T., et al. 2019. Polymers (Basel). 11: PMID: 31554305
  6. An Arthrobacter citreus strain suitable for degrading ε-caprolactam in polyamide waste and accumulation of glutamic acid.  |  Baxi, NN., et al. 2019. AMB Express. 9: 161. PMID: 31605246
  7. Photochromic Polyamide 6 Based on Spiropyran Synthesized via Hydrolyzed Ring-Opening Polymerization.  |  Tian, S., et al. 2021. Polymers (Basel). 13: PMID: 34372100
  8. Fast and Clean Synthesis of Nylon-6/Synthetic Saponite Nanocomposites.  |  Madrid, A., et al. 2021. Materials (Basel). 15: PMID: 35009309
  9. Redesigned Hybrid Nylons with Optical Clarity and Chemical Recyclability.  |  Cywar, RM., et al. 2022. J Am Chem Soc. 144: 5366-5376. PMID: 35290039
  10. Organocatalytic Copolymerization of Cyclic Lysine Derivative and ε-Caprolactam toward Antibacterial Nylon-6 Polymers.  |  Lian, J., et al. 2022. ACS Macro Lett. 11: 46-52. PMID: 35574805
  11. Copolymerization-Regulated Hydrogen Bonds: A New Routine for High-Strength Copolyamide 6/66 Fibers.  |  Wang, Z., et al. 2022. Polymers (Basel). 14: PMID: 36080592
  12. Epsilon-Caprolactam- and Nylon Oligomer-Degrading Bacterium Brevibacterium epidermidis BS3: Characterization and Potential Use in Bioremediation.  |  Esikova, TZ., et al. 2023. Microorganisms. 11: PMID: 36838338
  13. Characterization of a New Pseudomonas Putida Strain Ch2, a Degrader of Toxic Anthropogenic Compounds Epsilon-Caprolactam and Glyphosate.  |  Esikova, TZ., et al. 2023. Microorganisms. 11: PMID: 36985223
  14. Design of an Ante-enhancer with an Azone-Mimic Structure using Ionic Liquid.  |  Oshizaka, T., et al. 2023. Pharm Res. 40: 1577-1586. PMID: 37081304
  15. Bioremediation of epsilon-caprolactam from nylon-6 waste water by use of Pseudomonas aeruginosa MCM B-407.  |  Kulkarni, RS. and Kanekar, PP. 1998. Curr Microbiol. 37: 191-4. PMID: 9688819

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

ε-Caprolactam, 100 g

sc-356201
100 g
$21.00

ε-Caprolactam, 250 g

sc-356201A
250 g
$27.00