Date published: 2025-10-21

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Divinylphenylphosphine (CAS 26681-88-9)

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CAS Number:
26681-88-9
Molecular Weight:
162.17
Molecular Formula:
C10H11P
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Divinylphenylphosphine is a phosphine ligand used in organometallic chemistry and catalysis research due to its electron-rich nature and ability to coordinate with transition metals. Its divinyl groups allow for the formation of complexes with metals, which are then studied for their catalytic properties in various reactions, including cross-coupling and polymerization processes. Researchers focus on the synthesis of novel metal complexes with divinylphenylphosphine to explore their efficiency, selectivity, and reactivity in catalytic systems. The compound′s performance in homogeneous catalysis, particularly in the development of new catalysts for the formation of carbon-carbon bonds, is of significant interest. Additionally, its role in the study of catalytic mechanisms and the fine-tuning of catalyst structures provides insights into the design of more environmentally friendly and sustainable chemical processes.


Divinylphenylphosphine (CAS 26681-88-9) References

  1. Template synthesis of 1,4,7-triphosphacyclononanes.  |  Edwards, PG., et al. 2006. J Am Chem Soc. 128: 3818-30. PMID: 16536558
  2. New superhindered polydentate polyphosphine ligands P(CH2CH2P(t)Bu2)3, PhP(CH2CH2P(t)Bu2)2, P(CH2CH2CH2P(t)Bu2)3, and their ruthenium(II) chloride complexes.  |  Gilbert-Wilson, R., et al. 2012. Inorg Chem. 51: 3239-46. PMID: 22339363
  3. Grafting of Maleic Anhydride onto Poly(vinylidene fluoride) Using Reactive Extrusion.  |  Zhang, C., et al. 2023. Molecules. 28: PMID: 36903492
  4. Exclusion of six-coordinate intermediates in the electrochemical reduction of CO2 catalyzed by [Pd (triphosphine)(CH3CN)](BF4) 2 complexes.  |  Bernatis, P. R., Miedaner, A., Haltiwanger, R. C., & DuBois, D. L. (1994). 1994. Organometallics,. 13(12): 4835-4843.
  5. Synthesis of a New Type of Water‐Soluble Phosphines by addition of hydrophilic thiols to vinylphosphines. Preparation of the rhodium and palladium complexes.  |  Paetzold, E., Michalik, M., & Oehme, G. 1997. ournal für Praktische Chemie/Chemiker‐Zeitung. 339(1): 38-43.
  6. Annual survey of organometallic metal cluster chemistry for the year 1997  |  Richmond, M. G. 1998. Coordination chemistry reviews. 175(1): 271-322.
  7. Flame retardant polymer materials: An update and the future for 3D printing developments  |  Vahabi, H., Laoutid, F., Mehrpouya, M., Saeb, M. R., & Dubois, P. 2021. Materials Science and Engineering: R: Reports. 144: 100604.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Divinylphenylphosphine, 5 g

sc-257386
5 g
$520.00