Date published: 2025-12-5

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Dimethyl 3,4-furandicarboxylate (CAS 4282-33-1)

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Application:
Dimethyl 3,4-furandicarboxylate is a derivatized furan species
CAS Number:
4282-33-1
Purity:
≥94%
Molecular Weight:
184.15
Molecular Formula:
C8H8O5
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Dimethyl 3,4-furandicarboxylate is a furan compound that is useful as a diene for Diels-Alder transformations. Dimethyl 3,4-furandicarboxylate was employed as the precursor to a furan used as the diene in preparing dendrons and dendrimers based on reversible furan-maleimide Diels-Alder adducts, where Dimethyl 3,4-furandicarboxylate was reduced to the bis-hydroxymethyl species prior to dendron coupling.


Dimethyl 3,4-furandicarboxylate (CAS 4282-33-1) References

  1. Synthesis of indan-based unusual alpha-amino acid derivatives under phase-transfer catalysis conditions.  |  Kotha, S. and Brahmachary, E. 2000. J Org Chem. 65: 1359-65. PMID: 10814097
  2. Thermally responsive dendrons and dendrimers based on reversible furan-maleimide Diels-Alder adducts.  |  McElhanon, JR. and Wheeler, DR. 2001. Org Lett. 3: 2681-3. PMID: 11506608
  3. Self-sensitized photooxygenation of 3,4-dialkoxyfurans to vitamin C or its derivatives.  |  Hakimelahi, GH., et al. 2001. J Org Chem. 66: 7067-71. PMID: 11597231
  4. Synthesis of the carbocyclic core of the cornexistins by ring-closing metathesis.  |  Clark, JS., et al. 2003. Org Lett. 5: 89-92. PMID: 12509898
  5. The facile generation of a tetramethyleneethane type radical cation and biradical utilizing a 3,4-di(alpha-styryl)furan and a photoinduced ET and back ET sequence.  |  Ikeda, T., et al. 2008. J Am Chem Soc. 130: 2466-72. PMID: 18237165
  6. Selectivity Control in the Tandem Aromatization of Bio-Based Furanics Catalyzed by Solid Acids and Palladium.  |  Genuino, HC., et al. 2017. ChemSusChem. 10: 277-286. PMID: 27557889
  7. Synthesis of 3-benzoyl-4-benzylfurans structural related to furolignans.  |  Tufano, I., et al. 2020. Nat Prod Res. 34: 2109-2115. PMID: 30835542
  8. Synthesis of the Core Framework of the Cornexistins by Intramolecular Nozaki-Hiyama-Kishi Coupling.  |  Aimon, A., et al. 2019. Molecules. 24: PMID: 31336669

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Dimethyl 3,4-furandicarboxylate, 5 g

sc-239764
5 g
$116.00