Date published: 2026-5-3

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Dichlorophenylborane (CAS 873-51-8)

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Alternate Names:
Phenylboron dichloride; Phenyldichloroborane
CAS Number:
873-51-8
Purity:
≥95%
Molecular Weight:
158.82
Molecular Formula:
C6H5BCl2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Dichlorophenylborane, or 2,6-dichlorophenylborane, stands as an organic compound containing boron, widely employed across diverse scientific research realms. Its versatility shines as a reagent of choice in numerous synthetic reactions, spanning organic molecule synthesis and catalyst preparation. Additionally, its role extends to delving into the biochemical and physiological intricacies of various biological systems. The compound′s presence permeates scientific research, finding utility in crafting organic molecules including pharmaceuticals and catalysts. Moreover, it illuminates biochemical and physiological explorations, as evidenced by its impact on enzyme activity like acetylcholinesterase. The synthesis of nanoparticles, notably gold nanoparticles and quantum dots, further highlights its significance.


Dichlorophenylborane (CAS 873-51-8) References

  1. Highly selective asymmetric acetate aldol reactions of an N-acetyl thiazolidinethione reagent.  |  Zhang, Y., et al. 2004. Org Lett. 6: 23-5. PMID: 14703341
  2. Synthesis of a new N-acetyl thiazolidinethione reagent and its application to a highly selective asymmetric acetate aldol reaction.  |  Zhang, Y. and Sammakia, T. 2004. Org Lett. 6: 3139-41. PMID: 15330607
  3. Single-boron complexes of N-confused and N-fused porphyrins.  |  Młodzianowska, A., et al. 2007. Inorg Chem. 46: 6950-7. PMID: 17636897
  4. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines.  |  Giziroglu, E., et al. 2008. Inorg Chem. 47: 9751-3. PMID: 18841958
  5. New azaborine-thiophene heteroacenes.  |  Lepeltier, M., et al. 2010. Chem Commun (Camb). 46: 7007-9. PMID: 20730178
  6. Dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine-dichlorophenylborane.  |  Braunschweig, H., et al. 2009. Acta Crystallogr Sect E Struct Rep Online. 65: o2787. PMID: 21578380
  7. Total synthesis of (-)-irciniastatin B and structural confirmation via chemical conversion to (+)-irciniastatin A (psymberin).  |  An, C., et al. 2012. Org Lett. 14: 4350-3. PMID: 22892009
  8. 1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.  |  Wu, D., et al. 2015. Nat Commun. 6: 7340. PMID: 26073993
  9. Divergent Chemoenzymatic Synthesis of Asymmetrical-Core-Fucosylated and Core-Unmodified N-Glycans.  |  Li, T., et al. 2016. Chemistry. 22: 18742-18746. PMID: 27798819
  10. Engineered unnatural ubiquitin for optimal detection of deubiquitinating enzymes.  |  Rut, W., et al. 2020. Chem Sci. 11: 6058-6069. PMID: 32953009
  11. Activity profiling and crystal structures of inhibitor-bound SARS-CoV-2 papain-like protease: A framework for anti-COVID-19 drug design.  |  Rut, W., et al. 2020. Sci Adv. 6: PMID: 33067239
  12. Chemoenzymatic Synthesis of Complex N-Glycans of the Parasite S. mansoni to Examine the Importance of Epitope Presentation on DC-SIGN recognition.  |  Srivastava, AD., et al. 2021. Angew Chem Int Ed Engl. 60: 19287-19296. PMID: 34124805
  13. Reaction of Dichlorophenylborane with H-Si(100).  |  Frederick, E., et al. 2021. ACS Omega. 6: 33645-33651. PMID: 34926912
  14. Regioselective Reductive Opening of Benzylidene Acetals with Dichlorophenylborane/Triethylsilane: Previously Unreported Side Reactions and How to Prevent Them.  |  Hénault, J., et al. 2022. J Org Chem. 87: 963-973. PMID: 35015527
  15. Molecular basis for cell-wall recycling regulation by transcriptional repressor MurR in Escherichia coli.  |  Zhang, Y., et al. 2022. Nucleic Acids Res. 50: 5948-5960. PMID: 35640608

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Dichlorophenylborane, 1 g

sc-239705
1 g
$49.00

Dichlorophenylborane, 5 g

sc-239705A
5 g
$112.00