Molecular structure of Cyclopentylboronic acid, CAS Number: 63076-51-7
Cyclopentylboronic acid (CAS 63076-51-7)
CAS Number:
63076-51-7
Molecular Weight:
113.95
Molecular Formula:
C5H11BO2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
QUICK LINKS
Ordering Information
Description
Technical Information
Safety Information
SDS & Certificate of Analysis
Cyclopentylboronic acid is a boronic acid used as an organocatalyst in the synthesis of aromatic compounds. It exhibits reactivity towards chlorine and can engage in cross-coupling reactions with other boronic acids, halides, and trifluorides. Notably, this versatile compound enables the synthesis of functionalized aromatic hydrocarbons through palladium- or nickel-catalyzed reactions, utilizing tosylates or mesylates as starting materials. The use of cyclopentylboronic acid as an organocatalyst has been proven to enhance the efficiency of the coupling process.
Cyclopentylboronic acid (CAS 63076-51-7) References
- Cross coupling reactions of chiral secondary organoboronic esters with retention of configuration. | Imao, D., et al. 2009. J Am Chem Soc. 131: 5024-5. PMID: 19301820
- Straightforward synthetic access to gem-diaurated and digold σ,π-acetylide species. | Gómez-Suárez, A., et al. 2013. Angew Chem Int Ed Engl. 52: 938-42. PMID: 23180680
- Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes. | Takechi, R. and Nishimura, T. 2015. Chem Commun (Camb). 51: 8528-31. PMID: 25892197
- 1,n-Bisborylalkanes via Radical Boron Migration. | Wang, D., et al. 2020. J Am Chem Soc. 142: 9119-9123. PMID: 32363871
- Passerini-type reaction of boronic acids enables α-hydroxyketones synthesis. | Yang, K., et al. 2021. Nat Commun. 12: 441. PMID: 33469014
- A Boron Delivery Antibody (BDA) with Boronated Specific Residues: New Perspectives in Boron Neutron Capture Therapy from an In Silico Investigation. | Rondina, A., et al. 2021. Cells. 10: PMID: 34831449
- Cp*Rh(III)-Catalyzed C-H Arylation of Ferrocenethionamides with Aryl Boronic Acids for the Synthesis of Aryl-Ferrocenes. | Wang, Y., et al. 2023. Chem Asian J. 18: e202201180. PMID: 36495085
- Ruphos-mediated Suzuki cross-coupling of secondary alkyl trifluoroborates | Adri van den Hoogenband a, Jos H.M. Lange a, Jan Willem Terpstra a, Melle Koch b, Gerben M. Visser b, Martin Visser a, Ties J. Korstanje a, Johann T.B.H. Jastrzebski c. 2008. Tetrahedron Letters. 49: 4122-4124.
- Copper(I) 3-Methylsalicylate Mediates the Chan–Lam N-Arylation of Heterocycles | Abdelbasset A. Farahat & David W. Boykin. 2015. Synthetic Communications. 45: 245-252.
- Synthesis of asymmetrical dibenzothiophene sulfonate esters | John T. Petroff II, Ryan D. McCulla. 2016. Tetrahedron Letters. 57: 4723-4726.
- Phthalimide-Carried Disulfur Transfer To Synthesize Unsymmetrical Disulfanes via Copper Catalysis | Jiaoxia Zou, Jinhong Chen, Tao Shi*, Yongsheng Hou, Fei Cao, Yongqiang Wang, Xiaodong Wang, Zhong Jia, Quanyi ZhaoQuanyi ZhaoSchool of Pharmacy, Lanzhou University, West Donggang Road, No. 199, Lanzhou 730000, China, et al. 2019. ACS Catal. 9: 11426–11430.
- Visible-light-induced chemoselective reactions of quinoxalin-2 (1H)-ones with alkylboronic acids under air/N2 atmosphere | Lingling Yao a, Defeng Zhu a, Lei Wang a b, Jie Liu a, Yicheng Zhang a, Pinhua Li a c. 2021. Chinese Chemical Letters. 32: 4033-4037.
- Transition-Metal-Free DMAP-Mediated Aromatic Esterification of Amides with Organoboronic Acids | Tao Wang, Yanqing Wang, Kai Xu, Yuheng Zhang, Jiarui Guo, Prof. Lantao Liu. 2021. European Journal of Organic Chemistry. 14: 3274-3277.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Cyclopentylboronic acid, 1 g | sc-234480 | 1 g | $48.00 |