Date published: 2025-12-15

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Copper iodide dimethyl sulfide complex (CAS 914915-20-1)

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Alternate Names:
µ-Iodotri-µ3-iodotris[thiobis[methane]]tetracopper
Application:
Copper iodide dimethyl sulfide complex is a catalyst for conjugate addition reactions
CAS Number:
914915-20-1
Molecular Weight:
948.20
Molecular Formula:
C6H18Cu4I4S3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Copper iodide dimethyl sulfide complex (CuI-DMS) is a coordination compound consisting of copper, iodine, and dimethyl sulfide. This water-soluble compound has garnered significant attention in the scientific community due to its unique chemical structure and potential applications in various fields. In the field of photochemistry, Copper iodide dimethyl sulfide complex serves as a photosensitizer, enabling efficient energy transfer from light to chemical bonds. This property makes it valuable in catalyzing diverse reactions, including the generation of reactive oxygen species (ROS). Copper iodide dimethyl sulfide complex has also been investigated in the realm of electrochemistry as a redox mediator, facilitating the efficient transfer of electrons between two electrodes. This capability opens avenues for catalyzing various reactions, such as the oxidation of organic molecules. Furthermore, in materials science, Copper iodide dimethyl sulfide complex has been examined as a potential corrosion inhibitor. It has demonstrated efficacy in preventing the oxidation of metals like aluminum and copper across diverse environmental conditions.Although the exact mechanism of action for Copper iodide dimethyl sulfide complex is not yet fully understood, it is postulated that the complex acts as a ligand, binding to metal ions in solution and forming coordination complexes. These complexes are then capable of effectively transferring energy from light to chemical bonds, facilitating electron transfer between electrodes and promoting the oxidation of organic molecules.


Copper iodide dimethyl sulfide complex (CAS 914915-20-1) References

  1. Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes.  |  Vasilopoulos, A., et al. 2017. J Am Chem Soc. 139: 7705-7708. PMID: 28555493
  2. Addition of organocopper reagents to allylic acrylates - the preparation of γ, δ-unsaturated acids and subsequent functionalization to γ-lactones  |  M Eriksson, A Hjelmencrantz, M Nilsson, T Olsson - Tetrahedron, 1995 - Elsevier. 13 November 1995,. Tetrahedron. Volume 51, Issue 46,: Pages 12631-12644.
  3. Advancements in the Functionalization of Aryl C-sp2 and Alkyl C-sp3 of Toluene Derivatives via C-H Activation  |  George, Kevin; Kannadasan, Sathananthan. Number 15, 2021,. Current Organic Chemistry,. Volume 25,: pp. 1783-1822(40).
  4. Enantioselective synthesis of (R)- and (S)-curcumene and curcuphenol: an efficient chemoenzymatic route  |  Ahmed Kamal, M. Shaheer Malik, Ahmad Ali Shaik, Shaik Azeeza. 22 October 2007,. Tetrahedron: Asymmetry. Volume 18, Issue 21,: Pages 2547-2553.
  5. Catalytic enantioselective conjugate addition of Grignard reagents to cyclic α,β-unsaturated carbonyl compounds  |  M Kanai, Y Nakagawa, K Tomioka - Tetrahedron, 1999 - Elsevier. 26 March 1999,. Tetrahedron. Volume 55, Issue 13,: Pages 3843-3854.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Copper iodide dimethyl sulfide complex, 5 g

sc-234410
5 g
$138.00