Molecular structure of Cesium carbonate, CAS Number: 534-17-8
Cesium carbonate (CAS 534-17-8)
Alternate Names:
Carbonic acid dicesium
Application:
Cesium carbonate is a promoter of O-alkylation of alcohols
CAS Number:
534-17-8
Purity:
≥98%
Molecular Weight:
325.82
Molecular Formula:
Cs2CO3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Cesium carbonate promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates. It is a catalyst for aerobic oxidation of primary alcohols, 1,4-addition reactions, intramolecular C-N cross coupling reactions and dehydrohalogenative polycondensation reactions. Cesium carbonate, characterized by its white color, odorless nature, and crystalline structure, is a solid compound that readily dissolves in water, ethanol, and methanol.
Cesium carbonate (CAS 534-17-8) References
- Cesium carbonate-catalyzed alpha-phenylchalcogenation of carbonyl compounds with diphenyl dichalcogenide. | Nishiyama, Y., et al. 2009. Molecules. 14: 3367-75. PMID: 19783931
- Cesium carbonate functionalized graphene quantum dots as stable electron-selective layer for improvement of inverted polymer solar cells. | Yang, HB., et al. 2014. ACS Appl Mater Interfaces. 6: 1092-9. PMID: 24367967
- Cesium carbonate catalyzed chemoselective hydrosilylation of aldehydes and ketones under solvent-free conditions. | Zhao, M., et al. 2014. Chemistry. 20: 9259-62. PMID: 24989934
- An Alternative Method for Generating Arynes from ortho-Silylaryl Triflates: Activation by Cesium Carbonate in the Presence of a Crown Ether. | Yoshida, S., et al. 2015. Molecules. 20: 10131-40. PMID: 26039336
- Cesium carbonate-promoted synthesis of aryl methyl sulfides using S-methylisothiourea sulfate under transition-metal-free conditions. | Zhang, C., et al. 2018. Org Biomol Chem. 16: 6316-6321. PMID: 30128466
- Cesium Carbonate-Catalyzed Oxidation of Substituted Phenylsilanes for the Efficient Synthesis of Polyhedral Oligomeric Silsesquioxanes. | Li, Y. and Cui, C. 2018. Inorg Chem. 57: 13477-13485. PMID: 30351062
- Cesium-Carbonate-Mediated Benzalation of Substituted 2-Aryl-3-nitro-2 H-chromenes with Substituted 4-Benzylidene-2-phenyloxazol-5(4 H)-ones. | Dai, C., et al. 2019. Org Lett. 21: 2828-2832. PMID: 30939016
- Cesium Carbonate Catalyzed Esterification of N-Benzyl-N-Boc-amides under Ambient Conditions. | Ye, D., et al. 2019. Org Lett. 21: 6888-6892. PMID: 31407912
- Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs. | C, A., et al. 2020. Polymers (Basel). 13: PMID: 33379190
- Photocatalytic Reductive C-O Bond Cleavage of Alkyl Aryl Ethers by Using Carbazole Catalysts with Cesium Carbonate. | Yabuta, T., et al. 2021. J Org Chem. 86: 2545-2555. PMID: 33439026
- α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base. | Dhakshinamoorthy, A., et al. 2021. Nanomaterials (Basel). 11: PMID: 34070463
- Cesium carbonate mediated C-H functionalization of perhalogenated 12-vertex carborane anions. | Lovera, SO., et al. 2022. Chem Commun (Camb). 58: 4060-4062. PMID: 35262161
- Correction: Cesium carbonate mediated C-H functionalization of perhalogenated 12-vertex carborane anions. | Lovera, SO., et al. 2022. Chem Commun (Camb). 58: 6558. PMID: 35605976
- Cesium carbonate-catalyzed synthesis of phosphorothioates via S-phosphination of thioketones. | Chen, ZW., et al. 2022. Chem Commun (Camb). 58: 11001-11004. PMID: 36093933
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KIR3DL1.Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Cesium carbonate, 5 g | sc-252557 | 5 g | $20.00 | |||
Cesium carbonate, 25 g | sc-252557A | 25 g | $50.00 |