Date published: 2025-11-30

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Bromopentacarbonylrhenium(I) (CAS 14220-21-4)

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Alternate Names:
Pentacarbonylbromorhenium; Pentacarbonylrhenium bromide; Rhenium(I) pentacarbonyl bromide
Application:
Bromopentacarbonylrhenium(I) is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands
CAS Number:
14220-21-4
Molecular Weight:
406.16
Molecular Formula:
C5BrO5Re
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Bromopentacarbonylrhenium(I) is a metal carbonyl complex with applications in the field of organometallic chemistry and catalysis research. This compound is composed of a rhenium center coordinated to five carbonyl (CO) ligands and one bromine atom. In research, bromopentacarbonylrhenium(I) is utilized for its catalytic properties in various reactions, including olefin metathesis and the reduction of carbon dioxide. It is also a precursor for the synthesis of other rhenium complexes, which are studied for their potential as catalysts in organic synthesis. The complex is of interest in materials science as well, where it may be used in the development of new materials with electronic or photonic properties. Furthermore, the study of bromopentacarbonylrhenium(I) contributes to the understanding of the bonding and reactivity of transition metal carbonyls.


Bromopentacarbonylrhenium(I) (CAS 14220-21-4) References

  1. Reaction of bromopentacarbonylrhenium(I) with ferrocenylcarbaldehyde thiosemicarbazones: the first X-ray diffraction studies of metal carbonyl complexes containing bidentate thiosemicarbazone ligands  |  R Carballo, JS Casas, E Garcı́a-Martı́nez. 2002. Journal of Organometallic Chemistry. 656: 1-10.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Bromopentacarbonylrhenium(I), 1 g

sc-239429
1 g
$201.00

Bromopentacarbonylrhenium(I), 5 g

sc-239429A
5 g
$790.00