Molecular structure of Bromopentacarbonylmanganese(I), CAS Number: 14516-54-2
Bromopentacarbonylmanganese(I) (CAS 14516-54-2)
Alternate Names:
Manganese pentacarbonyl bromide
CAS Number:
14516-54-2
Molecular Weight:
274.89
Molecular Formula:
BrMn(CO)5
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.
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Bromopentacarbonylmanganese(I) is a metal complex composed of bromide and pentacarbonylmanganese. This low-valent metal complex features a metal-carbon bond order of three, and is a potent reducing agent. Its unique properties and broad range of applications in various fields have made it the subject of extensive laboratory research. Bromopentacarbonylmanganese(I) is employed as a catalyst in organic synthesis, as a reducing agent in metal-catalyzed reactions, and as a reagent in the synthesis of metal-organic frameworks. It is also used in the investigation of metal-ligand interactions in various systems, including organometallic complexes, coordination polymers systems, and metal-organic frameworks.
Bromopentacarbonylmanganese(I) (CAS 14516-54-2) References
- Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal-Organic Framework. | Fei, H., et al. 2015. Inorg Chem. 54: 6821-8. PMID: 26135673
- Manganese-Catalyzed Carboacylations of Alkenes with Alkyl Iodides. | McMahon, CM., et al. 2016. Org Lett. 18: 4148-50. PMID: 27505233
- Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes. | Ngo, KT., et al. 2017. J Am Chem Soc. 139: 2604-2618. PMID: 28118005
- Eradication of HT-29 colorectal adenocarcinoma cells by controlled photorelease of CO from a CO-releasing polymer (photoCORP-1) triggered by visible light through an optical fiber-based device. | Pinto, MN., et al. 2017. J Control Release. 264: 192-202. PMID: 28866022
- Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones. | Martínez-Ferraté, O., et al. 2018. ChemCatChem. 10: 4514-4518. PMID: 30443274
- Directing-Group-Assisted Manganese-Catalyzed Cyclopropanation of Indoles. | Dutta, PK., et al. 2019. Org Lett. 21: 2025-2028. PMID: 30860389
- Cooperative Mn(i)-complex catalyzed transfer hydrogenation of ketones and imines. | Ganguli, K., et al. 2019. Dalton Trans. 48: 7358-7366. PMID: 30941379
- An Investigation of Electrocatalytic CO2 Reduction Using a Manganese Tricarbonyl Biquinoline Complex. | McKinnon, M., et al. 2019. Front Chem. 7: 628. PMID: 31608271
- Water-assisted stability of carbene: cyclic voltammetric investigation of 1-ethyl-3-methylimidazolium ethylsulfate ionic liquid. | Jain, P., et al. 2019. Phys Chem Chem Phys. 21: 24126-24131. PMID: 31657400
- Photoactivatable Surface-Functionalized Diatom Microalgae for Colorectal Cancer Targeted Delivery and Enhanced Cytotoxicity of Anticancer Complexes. | Delasoie, J., et al. 2020. Pharmaceutics. 12: PMID: 32466116
- Cytotoxicity of Mn-based photoCORMs of ethynyl-α-diimine ligands against different cancer cell lines: The key role of CO-depleted metal fragments. | Rossier, J., et al. 2020. J Inorg Biochem. 209: 111122. PMID: 32497818
- CO release from Mn(i)-based photoCORMs with single photons in the phototherapeutic region. | Stenger-Smith, J., et al. 2021. Chem Commun (Camb). 57: 1101-1104. PMID: 33459308
- A Tumor Microenvironment Destroyer for Efficient Cancer Suppression. | Yao, H., et al. 2020. ACS Biomater Sci Eng. 6: 450-462. PMID: 33463237
- N-Alkylation of Amines with Alcohols Catalyzed by Manganese(II) Chloride or Bromopentacarbonylmanganese(I). | Wei, D., et al. 2021. J Org Chem. 86: 2254-2263. PMID: 33494595
- Efficient Hydrogenation of N-Heterocycles Catalyzed by NNP-Manganese(I) Pincer Complexes at Ambient Temperature. | Papa, V., et al. 2023. Chemistry. 29: e202202774. PMID: 36193859
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Bromopentacarbonylmanganese(I), 1 g | sc-227532A | 1 g | $218.00 | |||
Bromopentacarbonylmanganese(I), 5 g | sc-227532 | 5 g | $530.00 |