![Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] (CAS 819050-89-0) - chemical structure image](https://media.scbt.com/product/bisrhodiumalpha-alpha-alphaprime-alphaprime-tetramethyl-1-3-benzenedipropionic-acid-819050-89-0-structure_12_19_b_121958.jpg)
![Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] (CAS 819050-89-0) - chemical structure image](https://media.scbt.com/product/bisrhodiumalpha-alpha-alphaprime-alphaprime-tetramethyl-1-3-benzenedipropionic-acid-819050-89-0-structure_12_19_t_121958.jpg "Molecular structure of Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)], CAS Number: 819050-89-0")
Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] (CAS 819050-89-0)
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Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] is an organometallic complex of rhodium, which is a rare earth metal of the transition group. It serves as a catalyst for an efficient intermolecular amination of tertiary, benzylic C-H bonds. Additionally, it has been studied for use in the detection of metal ions in biological systems. The complex acts as a Lewis acid, which can coordinate to a Lewis base, such as a carbonyl group. This coordination allows for the formation of a rhodium-carbonyl intermediate, which can then undergo a variety of reactions, depending on the reaction conditions. The complex also has both antioxidant and anti-inflammatory properties, as it may act to scavenge free radicals and inhibit the production of pro-inflammatory cytokines in vitro.
Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)] (CAS 819050-89-0) References
- A concise synthesis of (-)-oseltamivir. | Trost, BM. and Zhang, T. 2008. Angew Chem Int Ed Engl. 47: 3759-61. PMID: 18399551
- Chemoselective aromatic C-H insertion of α-diazo-β-ketoesters catalyzed by dirhodium(II) carboxylates. | Rodriguez-Cárdenas, E., et al. 2012. Org Lett. 14: 238-40. PMID: 22128849
- Recent developments in the synthesis and application of sultones. | Mondal, S. 2012. Chem Rev. 112: 5339-55. PMID: 22742473
- Capturing fleeting intermediates in a catalytic C-H amination reaction cycle. | Perry, RH., et al. 2012. Proc Natl Acad Sci U S A. 109: 18295-9. PMID: 23091019
- Rhodium(ii)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans. | Marichev, KO., et al. 2018. Chem Commun (Camb). 54: 9513-9516. PMID: 30091758
- Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(ii) catalysts. | Berndt, JP., et al. 2019. Chem Sci. 10: 3324-3329. PMID: 30996919
- Diazoacetonitrile (N2 CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis. | Mykhailiuk, PK. and Koenigs, RM. 2020. Chemistry. 26: 89-101. PMID: 31415714
- Tandem Insertion-[1,3]-Rearrangement: Highly Enantioselective Construction of α-Aminoketones. | Chen, Y., et al. 2020. Angew Chem Int Ed Engl. 59: 8052-8056. PMID: 32125755
- Strain-Induced Nucleophilic Ring Opening of Donor-Acceptor Cyclopropenes for Synthesis of Monosubstituted Succinic Acid Derivatives. | Marichev, KO., et al. 2021. Chemistry. 27: 340-347. PMID: 32853426
- Tricyclic 2-benzazepines obtained via an unexpected cyclization involving nitrilium ylides. | Inyutina, A., et al. 2021. Org Biomol Chem. 19: 5068-5071. PMID: 34027962
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Bis[rhodium(α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid)], 100 mg | sc-252486 | 100 mg | $167.00 |