Date published: 2025-12-5

1-800-457-3801

SCBT Portrait Logo
Seach Input

Bismuth(III) trifluoromethanesulfonate (CAS 88189-03-1)

0.0(0)
Write a reviewAsk a question

Alternate Names:
Bismuth tris(trifluoromethanesulfonate)
Application:
Bismuth(III) trifluoromethanesulfonate is a direct substitution catalyst
CAS Number:
88189-03-1
Molecular Weight:
656.19
Molecular Formula:
C3BiF9O9S3
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Available in US only.
* Refer to Certificate of Analysis for lot specific data.

QUICK LINKS

Bismuth(III) trifluoromethanesulfonate, known as BTFMS, presents as a white, crystalline solid with solubility in water and various organic solvents. This versatile organosulfur compound is extensively utilized as a reagent in organic synthesis due to its potent oxidizing capabilities. Furthermore, Bismuth(III) trifluoromethanesulfonate finds application in analytical chemistry and biochemistry. Bismuth(III) trifluoromethanesulfonate plays a pivotal role in a myriad of scientific research applications, encompassing inorganic and organic synthesis, analytical chemistry, and biochemistry. In the realm of organic synthesis, its powerful oxidizing properties facilitate the oxidation of organic compounds. Within analytical chemistry, it serves as a valuable reagent for the determination of metal ions. Additionally, in biochemistry, Bismuth(III) trifluoromethanesulfonate is instrumental in analyzing catecholamines and other vital biological compounds. As a robust oxidizing agent, Bismuth(III) trifluoromethanesulfonate operates through an electron transfer mechanism. During the reaction, electrons are transferred from the organic compound to the Bismuth(III) trifluoromethanesulfonate molecule, culminating in the oxidation of the organic compound.


Bismuth(III) trifluoromethanesulfonate (CAS 88189-03-1) References

  1. Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides.  |  Qin, H., et al. 2007. Angew Chem Int Ed Engl. 46: 409-13. PMID: 17146812
  2. Formation of epoxide-amine oligo-adducts as OH-functionalized initiators for the ring-opening polymerization of ε-caprolactone.  |  Theis, J. and Ritter, H. 2010. Beilstein J Org Chem. 6: 938-44. PMID: 21085507
  3. Synthesis of trans-1,3-diaryl-2-(5-methylisoxazol-3-yl)-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazines via bismuth(III)-catalyzed one-pot pseudo-four component reaction.  |  Shafiee, M., et al. 2012. Mol Divers. 16: 727-35. PMID: 23090419
  4. A Concise Synthesis of Potential COX Inhibitor BRL-37959 and Analogs Involving Bismuth(III) Catalyzed Friedel-Crafts Acylation.  |  Ahmed, SA., et al. 2018. Chem Biodivers. 15: e1800334. PMID: 30239128
  5. Evaluation of click chemistry microarrays for immunosensing of alpha-fetoprotein (AFP).  |  Dadfar, SMM., et al. 2019. Beilstein J Nanotechnol. 10: 2505-2515. PMID: 31921529
  6. Functional Polymers and Polymeric Materials From Renewable Alpha-Unsaturated Gamma-Butyrolactones.  |  Kollár, J., et al. 2019. Front Chem. 7: 845. PMID: 31921769
  7. Bismuth(iii) triflate as a novel and efficient activator for glycosyl halides.  |  Steber, HB., et al. 2021. Org Biomol Chem. 19: 3220-3233. PMID: 33885577
  8. Use of Novel Non-Toxic Bismuth Catalyst for the Preparation of Flexible Polyurethane Foam.  |  El Khezraji, S., et al. 2021. Polymers (Basel). 13: PMID: 34961011
  9. Smart Anticorrosion Coatings Based on Poly(phenylene methylene): An Assessment of the Intrinsic Self-Healing Behavior of the Copolymer.  |  D'Elia, MF., et al. 2022. Polymers (Basel). 14: PMID: 36080534
  10. Recent progress in the chemistry of β-aminoketones.  |  Hammouda, MM. and Elattar, KM. 2022. RSC Adv. 12: 24681-24712. PMID: 36128366
  11. Plants Utilize Suberin Biopolymers as a Vector for Transmitting Visible Light through Their Roots.  |  Waller, S., et al. 2022. Polymers (Basel). 14: PMID: 36559753
  12. Fabrication of dialysis membrane from cotton Giza 86 cellulose di-acetate prepared using Ac2O and NiCl2 as a new catalyst.  |  Ragab, S., et al. 2023. Sci Rep. 13: 2276. PMID: 36755140
  13. Influence of Peripheral Alkyl Groups on Junction Configurations in Single-Molecule Electronics.  |  Ornago, L., et al. 2024. J Phys Chem C Nanomater Interfaces. 128: 1413-1422. PMID: 38293692

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Bismuth(III) trifluoromethanesulfonate, 5 g

sc-257167
5 g
$55.00
US: Only available in the US