Date published: 2026-4-4

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[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct (CAS 866395-16-6)

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Alternate Names:
[Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct
CAS Number:
866395-16-6
Molecular Weight:
1570.93
Molecular Formula:
(C20H15AuF6NO4PS2)2•C7H8
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Bis(trifluoromethanesulfonyl)imidate(triphenylphosphine)gold(I) (2:1) toluene adduct is a catalyst in organic synthesis. It functions as a source of gold in various reactions, particularly in the activation of alkynes and allenes. The gold complex facilitates the activation of carbon-carbon multiple bonds, enabling the formation of new carbon-carbon and carbon-heteroatom bonds. Bis(trifluoromethanesulfonyl)imidate(triphenylphosphine)gold(I) (2:1) toluene adduct ′s mode of action involves the coordination of the gold center to the unsaturated substrate, leading to the activation of the bond and subsequent reactivity. The toluene adduct serves as a solvent, providing a suitable reaction environment for the gold-catalyzed transformations. This complex plays a role in promoting various organic transformations by facilitating the activation of unsaturated substrates through its gold center.


[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct (CAS 866395-16-6) References

  1. Discovery and initial structure-activity relationships of N-benzyl tricyclic indolines as antibacterials for methicillin-resistant Staphylococcus aureus.  |  Michael Barbour, P., et al. 2014. Bioorg Med Chem Lett. 24: 5602-5605. PMID: 25466183
  2. Synthesis of Allylic Amide Functionalized 2H-Chromenes and Coumarins Using a One-Pot Overman Rearrangement and Gold(I)-Catalyzed Hydroarylation.  |  Sharif, SA., et al. 2016. J Org Chem. 81: 9810-9819. PMID: 27680202

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct, 250 mg

sc-300241
250 mg
$125.00