Benzo-15-crown-5 (CAS 14098-44-3)
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Benzo-15-crown-5, also referred to as benzo-15-crown ether, represents a cyclic polyether compound with wide-ranging applications in both organic and inorganic chemistry. This compound is comprised of a five-membered ring consisting of alternating carbon and oxygen atoms, with a benzene ring attached to the central oxygen atom. Its utility extends to various synthetic and analytical processes, including the synthesis of organic compounds, catalysis, and chromatographic separations. Furthermore, benzo-15-crown-5 has served as useful in the study of how cyclic polyethers impact the structure and functionality of proteins, as well as in the examination of membrane proteins. The interaction of benzo-15-crown-5 with proteins has been observed through various mechanisms. These include binding to proteins through hydrogen bonding, electrostatic interactions, and hydrophobic interactions. Furthermore, it has demonstrated an ability to interact with lipids and the active sites of enzymes.
Benzo-15-crown-5 (CAS 14098-44-3) References
- Selective potassium ion recognition by benzo-15-crown-5 fluoroionophore/gamma-cyclodextrin complex sensors in water. | Yamauchi, A., et al. 2000. Anal Chem. 72: 5841-6. PMID: 11128945
- Hydration to benzo-15-crown-5, benzo-18-crown-6 and the benzo-18-crown-6-potassium ion complex in the low-polar organic solvents. | Kikuchi, Y., et al. 2001. Anal Sci. 17: 421-4. PMID: 11990620
- Crown ether appended cyclam receptors for cationic guests. | Bernhardt, PV. and Hayes, EJ. 2002. Inorg Chem. 41: 2892-902. PMID: 12033897
- Ion-transfer polarographic determination of successive formation constants of rubidium and cesium complexes with benzo-15-crown-5 and -18-crown-6 ethers in nitrobenzene. | Kudo, Y., et al. 2002. Anal Sci. 18: 1047-9. PMID: 12243403
- Development of a carbon paste electrode containing benzo-15-crown-5 for trace determination of the uranyl ion by using a voltammetric technique. | Agrahari, SK., et al. 2009. J AOAC Int. 92: 241-7. PMID: 19382582
- Water's role in reshaping a macrocycle's binding pocket: infrared and ultraviolet spectroscopy of benzo-15-crown-5-(H(2)O)(n) and 4'-aminobenzo-15-crown-5-(H(2)O)(n), n = 1, 2. | Shubert, VA., et al. 2009. J Phys Chem A. 113: 8067-79. PMID: 19552395
- A comparison of complexation of Li+ ion with macrocyclic ligands 15-crown-5 and 12-crown-4 in binary nitromethane-acetonitrile mixtures by using lithium-7 NMR technique and ab initio calculation. | Alizadeh, N. 2011. Spectrochim Acta A Mol Biomol Spectrosc. 78: 488-93. PMID: 21146449
- Bis(benzo-15-crown-5-κO)strontium bis-(triiodide). | Walbaum, C., et al. 2008. Acta Crystallogr Sect E Struct Rep Online. 64: m747. PMID: 21202264
- Synthesis of some novel quinone diimine derivatives of benzo-15-crown-5 for application in Hg(2+) recognition. | Jagadale, SD., et al. 2014. Luminescence. 29: 586-90. PMID: 24123997
- Solvent Effects on the Encapsulation of Divalent Ions by Benzo-18-Crown-6 and Benzo-15-Crown-5. | Inokuchi, Y., et al. 2015. J Phys Chem A. 119: 8097-105. PMID: 26135940
- Spectral investigation of the effect of anion on the stability of non covalent assemblies of 2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine (benzo-15-crown-5) with sodium halides. | Ghildiyal, N., et al. 2017. Spectrochim Acta A Mol Biomol Spectrosc. 171: 507-514. PMID: 27591702
- Electrochemically Regulated Li Deposition by Crown Ether. | Lan, Q., et al. 2021. ACS Appl Mater Interfaces. 13: 15872-15880. PMID: 33759492
- Chromatographic Purification of Lithium, Vanadium, and Uranium from Seawater Using Organic Composite Adsorbents Composed of Benzo-18-Crown-6 and Benzo-15-Crown-5 Embedded in Highly Porous Silica Beads. | Tachibana, Y., et al. 2022. ACS Omega. 7: 27410-27421. PMID: 35967073
- Photonuclear Alchemy: Obtaining Medical Isotopes of Gold from Mercury Irradiated on Electron Accelerators. | Kazakov, AG., et al. 2022. Molecules. 27: PMID: 36080299
- Solvent-polarity reconfigurable fluorescent 4-piperazino-N-aryl-1,8-naphthalimide crown ether logic gates. | Gauci, G. and Magri, DC. 2022. RSC Adv. 12: 35270-35278. PMID: 36540226
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
Benzo-15-crown-5, 5 g | sc-252417 | 5 g | $140.00 |