Date published: 2025-11-9

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Ammonium tetraphenylborate (CAS 14637-34-4)

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Alternate Names:
Azanium tetraphenylboranuide
CAS Number:
14637-34-4
Molecular Weight:
337.27
Molecular Formula:
C24H20B•NH4
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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Ammonium tetraphenylborate is an organic salt formed from ammonium and tetraphenylborate, and it serves a wide range of purposes in laboratory applications. It exhibits solubility in water, alcohol, and ether. Researchers employ it as a reagent in the synthesis of organic compounds like amines and alcohols. Additionally, it acts as a catalyst in producing various substances, including polymers and dyes. Moreover, this compound plays a role in the preparation of diverse metal complexes, such as those involving cobalt, nickel, and zinc.


Ammonium tetraphenylborate (CAS 14637-34-4) References

  1. Short N+--H..Ph hydrogen bonds in ammonium tetraphenylborate characterized by neutron diffraction.  |  Steiner, T. and Mason, SA. 2000. Acta Crystallogr B. 56 (Pt 2): 254-60. PMID: 10794279
  2. Self-assembled ionophores from isoguanosine: diffusion NMR spectroscopy clarifies cation's and anion's influence on supramolecular structure.  |  Evan-Salem, T., et al. 2007. Chemistry. 13: 1969-77. PMID: 17136779
  3. Investigation of alkali metal and ammonium tetraphenylborates by infrared spectrophotometry.  |  Kiss-Eröss, K., et al. 1970. Talanta. 17: 1209-12. PMID: 18960852
  4. Ammonium tetraphenylborate-naphthalene adsorbent for the preconcentration and trace determination of iron in alloys and biological samples using 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol by third derivative spectrophotometry.  |  Ali Taher, M. and Krishan Puri, B. 1996. Talanta. 43: 247-53. PMID: 18966485
  5. Trace determination of zinc in standard alloys, environmental and pharmaceutical samples by fourth derivative spectrophotometry using 1-2-(thiazolylazo)-2-naphthol as reagent and ammonium tetraphenylborate supported on naphthalene as adsorbent.  |  Bhalotra, A. and Puri, BK. 1999. Talanta. 49: 485-93. PMID: 18967622
  6. Atomic absorption spectrometric determination of ultra trace amounts of zinc after preconcentration with the ion pair of 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol and ammonium tetraphenylborate on microcrystalline naphthalene or by column method.  |  Taher, MA. 2000. Talanta. 52: 181-8. PMID: 18967975
  7. Cationic rare-earth metal SALEN complexes.  |  Liu, Q., et al. 2008. Dalton Trans. 6170-8. PMID: 18985250
  8. Flow injection potentiometric determination of pancuronium bromide in pharmaceutical preparation and urine samples using modified carbon paste electrodes.  |  Zayed, SI. 2011. Chem Pharm Bull (Tokyo). 59: 254-9. PMID: 21297308
  9. Heteroatomic molecular clusters derived from Group 15 Zintl ion cages: synthesis and isolation of [M2(HP7)2](2-) (M=Ag, Au), two novel cluster anions exhibiting metallophilic interactions.  |  Knapp, CM., et al. 2011. Inorg Chem. 50: 4021-8. PMID: 21425807
  10. Isolation and stable nitrogen isotope analysis of ammonium ions in ammonium nitrate prills using sodium tetraphenylborate.  |  Howa, JD., et al. 2014. Rapid Commun Mass Spectrom. 28: 1530-4. PMID: 24861604
  11. Plasma-polymerized membrane electrode for the determination of dextromethorphan and dimemorfan.  |  Hazemoto, N., et al. 1989. Chem Pharm Bull (Tokyo). 37: 2153-4. PMID: 2598314
  12. Syntheses and Reactivity of New Zwitterionic Imidazolium Trihydridoborate and Triphenylborate Species.  |  Pellei, M., et al. 2020. Molecules. 25: PMID: 32668604
  13. Uptake of quaternary ammonium compounds into rat liver plasma membrane vesicles.  |  Ruifrok, PG. 1982. Biochem Pharmacol. 31: 1431-5. PMID: 7092932

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Ammonium tetraphenylborate, 10 g

sc-227261
10 g
$90.00