Date published: 2025-10-16

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Allyl bromide (CAS 106-95-6)

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CAS Number:
106-95-6
Purity:
≥99%
Molecular Weight:
120.98
Molecular Formula:
C3H5Br
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
Available in US only.
* Refer to Certificate of Analysis for lot specific data.

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Allyl bromide is a chemical used extensively in organic synthesis research due to its ability to introduce an allyl group into a compound. In the field of materials science, researchers employ allyl bromide in the preparation of polymers and resins, utilizing its reactive properties for polymerization reactions. It serves as a starting material in the study of palladium-catalyzed coupling reactions, which are significant for constructing carbon-carbon bonds in complex organic molecules. Additionally, allyl bromide is involved in the synthesis of pharmaceutical intermediates and agrochemicals in an industrial research context. Environmental scientists also study the impact and behavior of allyl bromide in the atmosphere, focusing on its photochemical reactions and potential to form larger organic compounds.


Allyl bromide (CAS 106-95-6) References

  1. Photodissociation dynamics of allyl bromide at 234, 265, and 267 nm.  |  Ji, L., et al. 2006. J Chem Phys. 125: 164307. PMID: 17092073
  2. Toxicology studies of allyl bromide (CAS No. 106-95-6) in genetically modified (FVB Tg.AC hemizygous) mice and carcinogenicity studies of allyl bromide in genetically modified [B6.129-Trp53tm1Brd (N5) Haploinsufficient] mice (dermal and gavage studies).  |  ,. 2008. Natl Toxicol Program Genet Modif Model Rep. 1-122. PMID: 18784760
  3. Indium and zinc-mediated Barbier-type addition reaction of 2,3-allenals with allyl bromide: an efficient synthesis of 1,5,6-alkatrien-4-ols.  |  Kong, W., et al. 2008. Org Biomol Chem. 6: 4587-92. PMID: 19039368
  4. Oxidation state, aggregation, and heterolytic dissociation of allyl indium reagents.  |  Koszinowski, K. 2010. J Am Chem Soc. 132: 6032-40. PMID: 20377261
  5. β-Cyclodextrin functionalized polystyrene porous monoliths for separating phenol from wastewater.  |  Han, J., et al. 2015. Carbohydr Polym. 120: 85-91. PMID: 25662691
  6. Nematicidal activity of allyl bromide and dibromo(nitro)methane under laboratory conditions.  |  Oka, Y., et al. 2016. Pest Manag Sci. 72: 57-66. PMID: 25754847
  7. One-pot preparation of trifluoromethylated homoallylic N-acylhydrazines or α-methylene-γ-lactams from acylhydrazines, trifluoroacetaldehyde methyl hemiacetal, allyl bromide and tin.  |  Du, G., et al. 2016. Org Biomol Chem. 14: 1492-500. PMID: 26690835
  8. Indium-Mediated Stereoselective Allylation.  |  Kumar, D., et al. 2016. Acc Chem Res. 49: 2169-2178. PMID: 27700084
  9. Hyperbranched Poly(ether-siloxane)s Containing Ammonium Groups: Synthesis, Characterization and Catalytic Activity.  |  Parzuchowski, PG., et al. 2020. Polymers (Basel). 12: PMID: 32272773
  10. Synthesis of trans-Mono(silyl)palladium(II) Bromide Complexes.  |  Ansell, MB., et al. 2021. Molecules. 26: PMID: 33922538
  11. Synthesis and crystal structure of allyl 7-(di-ethyl-amino)-2-oxo-2H-chromene-3-carboxyl-ate.  |  Nowatschin, V., et al. 2021. Acta Crystallogr E Crystallogr Commun. 77: 331-334. PMID: 33936752
  12. Preparation of Bis[(3-ethyl-3-methoxyoxetane)propyl]diphenylsilane and Investigation of Its Cationic UV-Curing Material Properties.  |  Liu, Y., et al. 2021. Polymers (Basel). 13: PMID: 34372177
  13. Unlocking Amides through Selective C-N Bond Cleavage: Allyl Bromide-Mediated Divergent Synthesis of Nitrogen-Containing Functional Groups.  |  Govindan, K., et al. 2021. Org Lett. 23: 9419-9424. PMID: 34784227
  14. Solvent-free synthesis and characterization of allyl chitosan derivatives.  |  Akopova, TA., et al. 2019. RSC Adv. 9: 20968-20975. PMID: 35515576
  15. A Thioether-Catalyzed Cross-Coupling Reaction of Allyl Halides and Arylboronic Acids.  |  Xu, J., et al. 2022. Angew Chem Int Ed Engl. 61: e202211408. PMID: 36042000

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

Allyl bromide, 250 g

sc-280596
250 g
$46.00
US: Only available in the US