Date published: 2025-12-18

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9-Fluorenone (CAS 486-25-9)

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Alternate Names:
Diphenylene ketone
Application:
9-Fluorenone is 9-Fluorenone is a polycyclic aromatic ketone that has photosensitizing properties and also has the ability to undergo electrochemical polymerization. 9-Fluorenone is used in industry as an initiator in visible-light cured resin systems. 9-Fluorenone has potentially toxic effects on humans, as exposure can cause DNA mutations.
CAS Number:
486-25-9
Molecular Weight:
180.20
Molecular Formula:
C13H8O
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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9-Fluorenone, a polycyclic aromatic ketone, is a compound of significant interest in various fields of scientific research, particularly in organic chemistry and materials science. This compound is characterized by a fluorene core with a carbonyl group at the 9-position, which alters its electronic and optical properties compared to its parent hydrocarbon, fluorene. 9-fluorenone has been extensively used to study photophysical properties and charge transfer mechanisms. Its ability to accept electrons makes it a valuable component in the development of organic semiconductors and photovoltaic materials. Studies often focus on how 9-fluorenone′s molecular structure can influence its efficiency and stability as an electron acceptor, which is crucial for enhancing the performance of organic electronic devices. Furthermore, 9-fluorenone has been employed as a building block in the synthesis of more complex organic molecules. Its reactive carbonyl group facilitates various chemical reactions, including condensation and addition reactions, making it a versatile reagent in synthetic organic chemistry. These reactions are pivotal for creating novel compounds with potential applications in creating new materials with specific desired properties. Additionally, the fluorescence properties of 9-fluorenone are exploited in spectroscopic studies, where it is used as a fluorescent probe to investigate molecular environments and dynamics. This application underscores its role in enhancing the understanding of molecular interactions and behaviors in complex systems.


9-Fluorenone (CAS 486-25-9) References

  1. Comparative radical production and cytotoxicity induced by camphorquinone and 9-fluorenone against human pulp fibroblasts.  |  Atsumi, T., et al. 2004. J Oral Rehabil. 31: 1155-64. PMID: 15544650
  2. Protective effects of antioxidants on micronuclei induced by irradiated 9-fluorenone/N,N-dimethyl-p-toluidine in CHO cells.  |  Li, YC., et al. 2008. J Biomed Mater Res B Appl Biomater. 84: 58-63. PMID: 17455275
  3. Effects of visible light-irradiated camphorquinone and 9-fluorenone on murine oral mucosa.  |  Okada, N., et al. 2008. Dent Mater J. 27: 809-13. PMID: 19241689
  4. Facile synthesis of picene from 1,2-di(1-naphthyl)ethane by 9-fluorenone-sensitized photolysis.  |  Okamoto, H., et al. 2011. Org Lett. 13: 2758-61. PMID: 21513300
  5. On the role of hydrogen bonds in photoinduced electron-transfer dynamics between 9-fluorenone and amine solvents.  |  Ghosh, HN., et al. 2012. Chemistry. 18: 4930-7. PMID: 22389093
  6. Vibrational dynamics of the CO stretching of 9-fluorenone studied by visible-pump and infrared-probe spectroscopy.  |  Fukui, Y., et al. 2015. Faraday Discuss. 177: 65-75. PMID: 25662747
  7. Mechanistic studies on the dibenzofuran formation from phenanthrene, fluorene and 9-fluorenone.  |  Li, S. and Zhang, Q. 2015. Int J Mol Sci. 16: 5271-84. PMID: 25756381
  8. Mechanochemical Reactions of Bis(9-methylphenyl-9-fluorenyl) Peroxides and Their Applications in Cross-Linked Polymers.  |  Lu, Y., et al. 2021. J Am Chem Soc. 143: 17744-17750. PMID: 34610739
  9. Synthesis of 9,9-bis(4-hydroxyphenyl) fluorene catalyzed by bifunctional ionic liquids.  |  Wei, J., et al. 2021. RSC Adv. 11: 32559-32564. PMID: 35493579
  10. Efficient regioselective five-component synthesis of novel thiazolo[3,2-a]pyridine carbohydrazides and oxazolo[3,2-a]pyridine carbohydrazides.  |  Rouzban, H., et al. 2023. Mol Divers. 27: 667-678. PMID: 35587848
  11. Synthesis of Thiomorpholine via a Telescoped Photochemical Thiol-Ene/Cyclization Sequence in Continuous Flow.  |  Steiner, A., et al. 2022. Org Process Res Dev. 26: 2532-2539. PMID: 36032361
  12. Oxygenated polycyclic aromatic hydrocarbons in food: toxicity, occurrence and potential sources.  |  Ma, X. and Wu, S. 2024. Crit Rev Food Sci Nutr. 64: 4882-4903. PMID: 36384378
  13. New fluorene-based bipolar charge transporting materials.  |  Jegorovė, A., et al. 2024. RSC Adv. 14: 2975-2982. PMID: 38239447

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

9-Fluorenone, 5 g

sc-397871
5 g
$34.00