Date published: 2025-9-5

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6-Bromo-2,2′-bipyridine (CAS 10495-73-5)

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Application:
6-Bromo-2,2′-bipyridine is a halogenated heterocycle
CAS Number:
10495-73-5
Purity:
97%
Molecular Weight:
235.08
Molecular Formula:
C10H7BrN2
Supplemental Information:
This is classified as a Dangerous Good for transport and may be subject to additional shipping charges.
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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6-Bromo-2,2′-bipyridine is a brominated bipyridine compound that plays a role in coordination chemistry and catalysis, particularly in the synthesis and development of coordination complexes and as a ligand in transition metal catalysis. This configuration allows it to act as a bidentate ligand, capable of coordinating with metal centers through the nitrogen atoms on the pyridine rings, forming stable, chelated complexes. These characteristics make 6-Bromo-2,2′-bipyridine a valuable compound in the study of molecular electronics, photovoltaics, and as a building block in the synthesis of more complex ligands and materials. Its use in creating metal complexes is essential for exploring new catalytic processes, advancing the understanding of reaction mechanisms, and developing new materials with tailored electronic and photophysical properties.


6-Bromo-2,2′-bipyridine (CAS 10495-73-5) References

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  2. 5'-substituted-6-carboxylic-2,2'-bipyridine acid: a pivotal architecton for building preorganized ligands.  |  Charbonnière, LJ., et al. 2002. J Org Chem. 67: 3933-6. PMID: 12027719
  3. Chiral 2,2'-bipyridines, 1,10-phenanthrolines, and 2,2':6',2' '-terpyridines: syntheses and applications in asymmetric homogeneous catalysis.  |  Chelucci, G. and Thummel, RP. 2002. Chem Rev. 102: 3129-70. PMID: 12222984
  4. Strong ferromagnetic exchange couplings in copper(II) and nickel(II) complexes with a paramagnetic tridentate chelate ligand, 2,2'-bipyridin-6-yl tert-butyl nitroxide.  |  Osanai, K., et al. 2006. J Am Chem Soc. 128: 14008-9. PMID: 17061866
  5. Self-assembly of transition metal ion complexes of a hybrid pyrazine-terpyridine ligand.  |  Stefankiewicz, AR., et al. 2013. Dalton Trans. 42: 1743-51. PMID: 23160345
  6. A polyaromatic terdentate binding unit with fused 5,6-membered chelates for complexing s-, p-, d-, and f-block cations.  |  Hoang, TN., et al. 2013. Inorg Chem. 52: 5570-80. PMID: 23600474
  7. Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding.  |  Zheng, S., et al. 2016. Chemistry. 22: 331-9. PMID: 26577340
  8. Synthesis and Isomeric Analysis of RuII Complexes Bearing Pentadentate Scaffolds.  |  Gil-Sepulcre, M., et al. 2016. Inorg Chem. 55: 11216-11229. PMID: 27715031
  9. Copper(i) and silver(i) complexes of 9,9-dimethyl-4,5-bis(di-tert-butylphosphino)xanthene: photophysical properties and structural rigidity under pressure.  |  Keller, S., et al. 2018. Photochem Photobiol Sci. 17: 375-385. PMID: 29457807
  10. Photophysical Properties of Pt(II) Polypyridines with Five- versus Six-Membered Chelate Rings: Trade-Offs in Angle Strain.  |  Natoli, SN., et al. 2018. Inorg Chem. 57: 6521-6529. PMID: 29749742
  11. Luminescent copper(i) complexes with bisphosphane and halogen-substituted 2,2'-bipyridine ligands.  |  Keller, S., et al. 2018. Dalton Trans. 47: 14263-14276. PMID: 29790540
  12. Aggregation of Ag(0) nanoparticles to unexpected stable chain-like assemblies mediated by 2,2'-bipyridine decorated peptoids.  |  Tigger-Zaborov, H. and Maayan, G. 2019. J Colloid Interface Sci. 533: 598-603. PMID: 30193146
  13. Slow spin crossover in bis-meridional Fe2+ complexes through spin-state auto-adaptive N6/N8 coordination.  |  Petzold, H., et al. 2018. Dalton Trans. 47: 17257-17265. PMID: 30488935
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Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

6-Bromo-2,2′-bipyridine, 1 g

sc-227052
1 g
$115.00

6-Bromo-2,2′-bipyridine, 5 g

sc-227052A
5 g
$420.00