5-(4-methoxyphenyl)dipyrromethane (CAS 176446-62-1)
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5-(4-methoxyphenyl)dipyrromethane is a pyrrole building block for the synthesis of porphyrins. It consists of a pyrrole ring and two phenyl groups, forming a five-membered heterocyclic hydrocarbon. This valuable reagent plays a role in the creation of heterocyclic compounds and organic dyes. It proves instrumental in the synthesis of various organic compounds, including polymers and dyes. Moreover, it serves as a building block for the development of organic catalysts and catalytic materials. The mechanism of action of 5-(4-methoxyphenyl)dipyrromethane involves the condensation of 4-methoxyphenol and pyrrole. This reaction takes place in an aqueous acetic acid solution at a temperature of 80°C. Remarkably, this process yields a remarkable 88% of the desired product, 5-(4-methoxyphenyl)dipyrromethane.
5-(4-methoxyphenyl)dipyrromethane (CAS 176446-62-1) References
- Efficient synthesis of meso-substituted corroles in a H2O-MeOH mixture. | Koszarna, B. and Gryko, DT. 2006. J Org Chem. 71: 3707-17. PMID: 16674040
- A new synthesis of porphyrins via a putative trans-manganese(iv)-dihydroxide intermediate. | Mondal, S., et al. 2020. Dalton Trans. 49: 1424-1432. PMID: 31915769
- Synthesis and Structure of [meso-Triarylcorrolato]silver(III) | Christian Brückner, Cheri A. Barta, Raymond P. Briñas, and Jeanette A. Krause Bauer. 2003. Inorg. Chem. 42: 1673–1680.
- Effects of aldehyde or dipyrromethane substituents on the reaction course leading to meso-substituted porphyrins | G. Richard Geier III †, Jonathan S. Lindsey. 2004. Tetrahedron. 60: 11435-11444.
- Efficient and versatile single pot approach to dipyrromethanes and bis(heterocyclyl)methanes | Kamaljit Singh, Sonia Behal, Maninder Singh Hundal †. 2005. Tetrahedron. 61: 6614-6622.
- Synthesis of meso-substituted dipyrromethanes using iodine-catalysis | Pierre-Antoine Faugeras, Benjamin Boëns, Pierre-Henri Elchinger, Julien Vergnaud, Karine Teste, Rachida Zerrouki. 2010. Tetrahedron Letters. 51: 4630-4632.
Ordering Information
| Product Name | Catalog # | UNIT | Price | Qty | FAVORITES | |
5-(4-methoxyphenyl)dipyrromethane, 1 g | sc-396885 | 1 g | $245.00 | |||
5-(4-methoxyphenyl)dipyrromethane, 5 g | sc-396885A | 5 g | $979.00 |