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4,4′-Bis(chloromethyl)-1,1′-biphenyl (CAS 1667-10-3)

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CAS Number:
1667-10-3
Molecular Weight:
251.15
Molecular Formula:
C14H12Cl2
For Research Use Only. Not Intended for Diagnostic or Therapeutic Use.
* Refer to Certificate of Analysis for lot specific data.

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4,4′-Bis(chloromethyl)-1,1′-biphenyl is a colorless solid characterized by a mild, sweet scent and is insoluble in water but has solubility in ethanol, acetone, and benzene. Its highly reactive nature facilitates interaction with nucleophiles, leading to substitution and elimination reactions. Additionally, its sensitivity to light enables it to partake in photochemical reactions. This compound is used as a crosslinking agent, a plasticizer, and a flame retardant in the production of numerous materials. It′s instrumental in the formulation of photosensitive materials, the synthesis of polymers, and the production of epoxy resinsThe compound has applications in various fields, including material science and electronics.


4,4′-Bis(chloromethyl)-1,1′-biphenyl (CAS 1667-10-3) References

  1. Phase-Transfer-Catalyzed Etherification of 4,4'-Bis(chloromethyl)-1,1'-biphenyl with 1-Butanol by Polymer-Supported Catalysis  |  Maw-Ling Wang, Ze-Fa Lee, and Feng-Sheng Wang. 2005,. Ind. Eng. Chem. Res. 44, 15,: 5417–5426.
  2. Hydrogen Storage in Microporous Hypercrosslinked Organic Polymer Networks  |  Colin D. Wood, Bien Tan, Abbie Trewin, Hongjun Niu, Darren Bradshaw, Matthew J. Rosseinsky, Yaroslav Z. Khimyak, Neil L. Campbell, Ralph Kirk, Ev Stöckel, and Andrew I. Cooper. 2007,. Chem. Mater. 19, 8,: 2034–2048.
  3. Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO2 capture  |  Claudia F. Martín,a Ev Stöckel,b Rob Clowes,c Dave J. Adams,b Andrew I. Cooper,bc Jose J. Pis,a Fernando Rubieraa and Cova Pevida*a. 2011,. J. Mater. Chem.,. 21,: 5475-5483.
  4. Reaction of 4,4′-bis(chloromethyl)-1,1′-biphenyl and phenol in two-phase medium via phase-transfer catalysis  |  ML Wang, ZF Lee - Journal of Molecular Catalysis A: Chemical, 2007 - Elsevier. 1 March 2007,. Journal of Molecular Catalysis A: Chemical. Volume 264, Issues 1–2,: Pages 119-127.
  5. Esterification of sodium 4-hydroxybenzoate by ultrasound-assisted solid–liquid phase-transfer catalysis using dual-site phase-transfer catalyst  |  HM Yang, WM Chu - Ultrasonics sonochemistry, 2014 - Elsevier. Issue 1, January 2014,. Ultrasonics Sonochemistry. Volume 21,: Pages 395-400.
  6. Tailoring the pore size distribution of self-cross-linked 4,4′-bis(chloromethyl)-1,1′-biphenyl polymers using reactive and non-reactive co-solvents  |  M Ghafari, JD Atkinson - Polymer, 2018 - Elsevier. 9 May 2018,. Polymer. Volume 143,: Pages 331-335.
  7. Phenol adsorption on α,α′-dichloro-p-xylene (DCX) and 4,4′-bis(chloromethyl)-1,1′-biphenyl (BCMBP) modified XAD-4 resins from aqueous solutions  |  . 15 April 2013,. Chemical Engineering Journal. Volume 222,: Pages 1-8.
  8. Hypercrosslinked β-cyclodextrin porous polymer as adsorbent for effective uptake towards albendazole from aqueous media  |  D Wang, G Chen, X Li, Q Jia - Separation and Purification Technology, 2019 - Elsevier. 15 November 2019,. Separation and Purification Technology. Volume 227,: 115720.
  9. Polyethyleneimine/4,4′-Bis(chloromethyl)-1,1′-biphenyl nanofiltration membrane for metal ions removal in acid wastewater  |  K Gu, S Pang, BB Yang, Y Ji, Y Zhou, C Gao - Journal of Membrane …, 2020 - Elsevier. 15 November 2020,. Journal of Membrane Science. Volume 614,: 118497.
  10. Enhanced recovery of acetophenone and 1‐phenylethanol from petrochemical effluent by highly porous starch-based hypercrosslinked polymers  |  L Zhou, K Chai, X Yao, H Ji - Chemical Engineering Journal, 2021 - Elsevier. 15 August 2021,. Chemical Engineering Journal. Volume 418,: 129351.
  11. Novel microporous hypercross-linked polymers as sorbent for volatile organic compounds and CO2 adsorption  |  R Vinodh, EM Jung, M Ganesh, MM Peng… - Journal of Industrial and …, 2015 - Elsevier. 25 January 2015,. Journal of Industrial and Engineering Chemistry. Volume 21,: Pages 1231-1238.
  12. Synthesis of novel multi-site phase-transfer catalyst and its application in the reaction of 4,4′-bis(chloromethyl)-1,1′-biphenyl with 1-butanol  |  ML Wang, ZF Lee, FS Wang - Journal of Molecular Catalysis A: Chemical, 2005 - Elsevier. 29 March 2005,. Journal of Molecular Catalysis A: Chemical. Volume 229, Issues 1–2,: Pages 259-269.
  13. Construction of hypercrosslinked polymers for high-performance solid phase microextraction of phthalate esters from water samples  |  J Li, Z Wang, Q Wang, L Guo, C Wang, Z Wang… - … of Chromatography A, 2021 - Elsevier. 29 March 2021,. Journal of Chromatography A. Volume 1641,: 461972.

Ordering Information

Product NameCatalog #UNITPriceQtyFAVORITES

4,4′-Bis(chloromethyl)-1,1′-biphenyl, 250 g

sc-226817
250 g
$67.00